利用层次化ZnCoTe中空纳米花的储能潜力

IF 8.9 2区 工程技术 Q1 ENERGY & FUELS Journal of energy storage Pub Date : 2025-04-10 Epub Date: 2025-02-15 DOI:10.1016/j.est.2025.115801
Nastaran Karimipour , Akbar Mohammadi Zardkhoshoui , Saied Saeed Hosseiny Davarani
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摘要

由于其优异的导电性和良好的电化学性能,混合金属碲化物(mmte)在超级电容器领域正成为人们关注的焦点。在此,我们报告了一种简单的自模板策略来创建分层ZnCoTe空心纳米花(ZCT)。我们的方法是使用ZnCo层状双氢氧化物纳米花(ZCLDH)合成ZCT,这些纳米结构被用作超级电容器的理想材料。Te在ZCT结构中的插入显著提高了ZCT的导电性。此外,ZCT的特殊形貌避免了粉化和聚集问题,确保了循环过程中的结构寿命。利用其结构和组成优势,ZCT展示了卓越的效率。它具有1152C g−1的惊人容量,并在28a g−1下保持77.75%的容量。此外,它还显示了令人印象深刻的90.12%的持久性。这项工作的一个重要成就是创建了一个混合器件((−)AC||ZCT(+))。该电池在800w kg - 1的功率密度下,暴露的能量密度(ED)为64wh kg - 1。这项研究为其他应用的碲基材料的制造开辟了道路。
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Exploiting the energy storage potential of hierarchical ZnCoTe hollow nanoflowers
Thanks to their exceptional electrical conductivity and desirable electrochemical behavior, mixed metal tellurides (MMTes) are acquiring the spotlight in supercapacitors. Herein, we report a facile self-templating strategy to create hierarchical ZnCoTe hollow nanoflowers (ZCT). Our procedure uses a ZnCo layered double hydroxide nanoflowers (ZCLDH) for synthesis of ZCT and these nanostructures are utilized as desirable materials for supercapacitors. The insertion of Te in the structure of ZCT notably enhances its conductivity. Besides, the special morphology of the ZCT circumvents the pulverization and aggregation issues and ensures structural longevity during cycling processes. Capitalizing on their structural as well as compositional advantages, the ZCT unveils excellent efficiency. It demonstrates a marvelous capacity of 1152C g−1 and preserves a good 77.75 % capacity retention at 28 A g−1. Also, it discloses an impressive lastingness of 90.12 %. An important accomplishment of this work is the creation of a hybrid device ((−)AC||ZCT(+)). This cell exposes an energy density (ED) of 64 Wh kg−1 at the power density (PD) of 800 W kg−1. This research opens avenues for the fabrication of telluride-based materials for other applications.
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来源期刊
Journal of energy storage
Journal of energy storage Energy-Renewable Energy, Sustainability and the Environment
CiteScore
11.80
自引率
24.50%
发文量
2262
审稿时长
69 days
期刊介绍: Journal of energy storage focusses on all aspects of energy storage, in particular systems integration, electric grid integration, modelling and analysis, novel energy storage technologies, sizing and management strategies, business models for operation of storage systems and energy storage developments worldwide.
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