利用优化的分子印迹聚合物高灵敏度和选择性检测异丙醇气体的双功能天线传感器

IF 9.1 1区 化学 Q1 CHEMISTRY, ANALYTICAL ACS Sensors Pub Date : 2025-02-20 DOI:10.1021/acssensors.4c03393
Mohammad Mahmudul Hasan, Onur Alev, Michael Cheffena
{"title":"利用优化的分子印迹聚合物高灵敏度和选择性检测异丙醇气体的双功能天线传感器","authors":"Mohammad Mahmudul Hasan, Onur Alev, Michael Cheffena","doi":"10.1021/acssensors.4c03393","DOIUrl":null,"url":null,"abstract":"Accurate monitoring of isopropanol (IPA) levels is crucial for safety in industrial and laboratory settings, as high concentrations can lead to serious health issues. In this study, we present, for the first time, a dual-functional antenna sensor capable of high-performance IPA gas detection with concentration estimation and uninterrupted wireless communication, using optimized molecularly imprinted polymer (MIP)/multiwalled carbon nanotube (MWCNT)-based sensing materials. Comprehensive characterization of these materials confirms the successful formation and homogeneity of the composites. Furthermore, the electrical and gas-sensing properties of the sensing materials were evaluated using functionalized interdigitated electrode (IDE)-based sensing structures, optimized for high sensitivity, were functionalized to evaluate the electrical and gas-sensing properties of the materials. These IDE structures, which acted as impedance-varying components during operation, were coupled with a single-port monopole antenna to develop a highly sensitive and selective gas sensor while maintaining uninterrupted communication services. The results showed that the fabricated sensor platform exhibits strong selectivity, sensitivity, and stability for IPA detection at room temperature, effectively distinguishing it from other interference gases. In addition, using the same sensing material, we demonstrated that the antenna-based gas sensor exhibited higher sensitivity than the chemiresistive sensor, achieving a detection limit (18.8 ppm) below the safety thresholds for IPA. Moreover, the antenna’s radiation pattern and communication capabilities remained unaffected, ensuring uninterrupted functionality. Detailed optimization process and the sensing mechanism for a novel MIP-based selective antenna gas sensor, supported by both structural and electrical characterizations could serve as a milestone for future studies and the advancement of next-generation sensors.","PeriodicalId":24,"journal":{"name":"ACS Sensors","volume":"170 1","pages":""},"PeriodicalIF":9.1000,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Dual-Functional Antenna Sensor for Highly Sensitive and Selective Detection of Isopropanol Gas Using Optimized Molecularly Imprinted Polymers\",\"authors\":\"Mohammad Mahmudul Hasan, Onur Alev, Michael Cheffena\",\"doi\":\"10.1021/acssensors.4c03393\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Accurate monitoring of isopropanol (IPA) levels is crucial for safety in industrial and laboratory settings, as high concentrations can lead to serious health issues. In this study, we present, for the first time, a dual-functional antenna sensor capable of high-performance IPA gas detection with concentration estimation and uninterrupted wireless communication, using optimized molecularly imprinted polymer (MIP)/multiwalled carbon nanotube (MWCNT)-based sensing materials. Comprehensive characterization of these materials confirms the successful formation and homogeneity of the composites. Furthermore, the electrical and gas-sensing properties of the sensing materials were evaluated using functionalized interdigitated electrode (IDE)-based sensing structures, optimized for high sensitivity, were functionalized to evaluate the electrical and gas-sensing properties of the materials. These IDE structures, which acted as impedance-varying components during operation, were coupled with a single-port monopole antenna to develop a highly sensitive and selective gas sensor while maintaining uninterrupted communication services. The results showed that the fabricated sensor platform exhibits strong selectivity, sensitivity, and stability for IPA detection at room temperature, effectively distinguishing it from other interference gases. In addition, using the same sensing material, we demonstrated that the antenna-based gas sensor exhibited higher sensitivity than the chemiresistive sensor, achieving a detection limit (18.8 ppm) below the safety thresholds for IPA. Moreover, the antenna’s radiation pattern and communication capabilities remained unaffected, ensuring uninterrupted functionality. Detailed optimization process and the sensing mechanism for a novel MIP-based selective antenna gas sensor, supported by both structural and electrical characterizations could serve as a milestone for future studies and the advancement of next-generation sensors.\",\"PeriodicalId\":24,\"journal\":{\"name\":\"ACS Sensors\",\"volume\":\"170 1\",\"pages\":\"\"},\"PeriodicalIF\":9.1000,\"publicationDate\":\"2025-02-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Sensors\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1021/acssensors.4c03393\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Sensors","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acssensors.4c03393","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0

摘要

准确监测异丙醇(IPA)水平对于工业和实验室环境中的安全至关重要,因为高浓度会导致严重的健康问题。在这项研究中,我们首次使用优化的分子印迹聚合物(MIP)/多壁碳纳米管(MWCNT)传感材料,提出了一种双功能天线传感器,能够进行高性能的IPA气体检测,具有浓度估计和不间断无线通信。这些材料的综合表征证实了复合材料的成功形成和均匀性。此外,利用基于功能化交叉指电极(IDE)的传感结构对传感材料的电和气敏性能进行了评估,并对其进行了高灵敏度优化,对材料的电和气敏性能进行了功能化评估。这些IDE结构在运行过程中充当阻抗变化组件,与单端口单极天线相结合,开发出高灵敏度和选择性的气体传感器,同时保持不间断的通信服务。结果表明,该传感器平台在室温下检测IPA具有较强的选择性、灵敏度和稳定性,能有效地将IPA与其他干扰气体区分开来。此外,使用相同的传感材料,我们证明了基于天线的气体传感器比化学电阻传感器具有更高的灵敏度,达到了低于IPA安全阈值的检测限(18.8 ppm)。此外,天线的辐射方向图和通信能力不受影响,确保不间断的功能。基于mip的新型选择性天线气体传感器的详细优化过程和传感机制,以及结构和电气特性的支持,可以作为未来研究和下一代传感器进步的里程碑。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Dual-Functional Antenna Sensor for Highly Sensitive and Selective Detection of Isopropanol Gas Using Optimized Molecularly Imprinted Polymers
Accurate monitoring of isopropanol (IPA) levels is crucial for safety in industrial and laboratory settings, as high concentrations can lead to serious health issues. In this study, we present, for the first time, a dual-functional antenna sensor capable of high-performance IPA gas detection with concentration estimation and uninterrupted wireless communication, using optimized molecularly imprinted polymer (MIP)/multiwalled carbon nanotube (MWCNT)-based sensing materials. Comprehensive characterization of these materials confirms the successful formation and homogeneity of the composites. Furthermore, the electrical and gas-sensing properties of the sensing materials were evaluated using functionalized interdigitated electrode (IDE)-based sensing structures, optimized for high sensitivity, were functionalized to evaluate the electrical and gas-sensing properties of the materials. These IDE structures, which acted as impedance-varying components during operation, were coupled with a single-port monopole antenna to develop a highly sensitive and selective gas sensor while maintaining uninterrupted communication services. The results showed that the fabricated sensor platform exhibits strong selectivity, sensitivity, and stability for IPA detection at room temperature, effectively distinguishing it from other interference gases. In addition, using the same sensing material, we demonstrated that the antenna-based gas sensor exhibited higher sensitivity than the chemiresistive sensor, achieving a detection limit (18.8 ppm) below the safety thresholds for IPA. Moreover, the antenna’s radiation pattern and communication capabilities remained unaffected, ensuring uninterrupted functionality. Detailed optimization process and the sensing mechanism for a novel MIP-based selective antenna gas sensor, supported by both structural and electrical characterizations could serve as a milestone for future studies and the advancement of next-generation sensors.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
ACS Sensors
ACS Sensors Chemical Engineering-Bioengineering
CiteScore
14.50
自引率
3.40%
发文量
372
期刊介绍: ACS Sensors is a peer-reviewed research journal that focuses on the dissemination of new and original knowledge in the field of sensor science, particularly those that selectively sense chemical or biological species or processes. The journal covers a broad range of topics, including but not limited to biosensors, chemical sensors, gas sensors, intracellular sensors, single molecule sensors, cell chips, and microfluidic devices. It aims to publish articles that address conceptual advances in sensing technology applicable to various types of analytes or application papers that report on the use of existing sensing concepts in new ways or for new analytes.
期刊最新文献
Integrated Biodevice for Parallel Magnetic Isolation and Bioelectrocatalytic Detection of Circulating DNA and RNA Biomarkers in Non-Small Cell Lung Cancer Liquid Biopsy. Accurate Phenotyping at the Single-Exosome Level Using a Proximity-Ligation RCA-Based Light-Scattering Counting Platform for Breast Cancer Diagnosis. MoS2 Heterojunction-Based Gas Sensor Platform Enables Real-Time Detection of Sarin at Room Temperature via Strong Adsorption and Enhanced Charge Transfer. A Synergistic Noise Suppression Strategy for High-Fidelity in Vivo Photoelectrochemical Brain Sensing. Monolithic Bionic Tactile Sensor for Simultaneous Recognition of Pressure, Temperature, and Texture.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1