IF 3.7 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Langmuir Pub Date : 2025-02-21 DOI:10.1021/acs.langmuir.4c04428
Liuzhen Ren, Jiangzhuo Ren, Luyao Bao, Jun Wen, Min Ye, Haibao Hu
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摘要

液-液界面(LLI)是造成流动滑移从而促进液体注入表面(LIS)阻力减小的关键,但它确实受到流动剪切力的影响。本研究采用横向多体耗散动力学模拟方法,探讨了 LLI 的剪切演变以及周期性沟槽 LIS 上相应的滑移。结果表明,相对较小的剪切率只能引起 LLI 的轻微变形,相应的有效滑移取决于剪切率。随着剪切速率的进一步增加,LLI 发生明显变形,一旦毛细力和剪切力之间的平衡被打破,下游三相接触线就会发生移动,从而导致滑移明显增加,特别是对于凸面 LLI 而言。与凸面 LLI 或凹面 LLI 相比,平面 LLI 在相同的剪切力作用下保持相对稳定,而粘度比的增加和 LLI 分量的减少都能增强 LLI 的抗剪切力,但它们对滑动的促进作用较弱。因此,目前的研究结果不仅表明滑移与界面挠度和剪切速率有关,还表明在设计有效的 LIS 时应同时考虑 LLI 的抗剪切性和滑移性。
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Shear Evolution and Slippage of the Liquid–Liquid Interface over a Liquid-Infused Surface: A Many-Body Dissipative Particle Dynamics Study
The liquid–liquid interface (LLI), which is the key to cause flow slippage and thus promote drag reduction of liquid-infused surfaces (LISs), does suffer from the action of flow shear. In the current study, the transverse many-body dissipative dynamics simulation method is applied to explore the shear evolution of LLI and the corresponding slippage over a periodically grooved LIS. Results show that a relatively small shear rate only induces a slight deformation of LLI and the corresponding effective slippage is dependent on the shear rate. With a further increase of the shear rate, LLI deforms apparently and then the downstream three phase contact line depins to move once the balance between the capillary force and the shear force is broken, which results in an apparent increase of the slippage, specifically for a convex LLI. Compared with a convex LLI or a concave LLI, a flat LLI remains relatively stable under the same shear action, and an increase of the viscosity ratio and a decrease of the LLI fraction can both strengthen the shear resistance of an LLI, while they are less effective to promote the slippage. Consequently, the current results not only indicate that the slippage is related to the interface deflection and the shear rate but also suggest that both the shear resistance and the slippage of LLI should be considered when designing an effective LIS.
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来源期刊
Langmuir
Langmuir 化学-材料科学:综合
CiteScore
6.50
自引率
10.30%
发文量
1464
审稿时长
2.1 months
期刊介绍: Langmuir is an interdisciplinary journal publishing articles in the following subject categories: Colloids: surfactants and self-assembly, dispersions, emulsions, foams Interfaces: adsorption, reactions, films, forces Biological Interfaces: biocolloids, biomolecular and biomimetic materials Materials: nano- and mesostructured materials, polymers, gels, liquid crystals Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do? Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*. This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).
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