1,2,4,5-四akis（二苯基膦）吡啶与Eu(III), Tb （III）和Gd（III）的新配位聚合物。合成及发光性能

IF 5.4 3区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Inorganic Chemistry Communications Pub Date : 2025-05-01 Epub Date: 2025-02-23 DOI:10.1016/j.inoche.2025.114156

V.K. Brel , O.I. Artyushin , E.V. Smirnova , E.E. Kim , A.V. Vologzhanina , M.T. Metlin , P.V. Dorovatovskii , I.V. Taydakov

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引用次数: 0

摘要

本文研究了一类由1,2,4,5-四（二苯基膦）吡啶与三价Eu（III）、Tb（III）和Gd（III）离子合成的新型配位聚合物。由于配体的桥接螯合性质，合成的聚合物具有独特的一维周期结构，并且具有显著的发光效率。铽和铕配合物表现出高量子产率和高纯度的发光色。因此，它们是光子器件（如需要高强度单色发射的oled）的有前途的材料。

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New coordination polymers of 1,2,4,5-tetrakis (diphenylphosphino)pyridine with Eu(III), Tb (III), and Gd(III). Synthesis and luminescent properties

This study presents a new class of coordination polymers synthesized from 1,2,4,5-tetrakis(diphenylphosphino)pyridine and trivalent Eu(III), Tb(III), and Gd(III) ions. The synthesized polymers exhibit a unique one-dimensional periodic structure enabled by the bridging chelate nature of the ligand, and a noteworthy luminescent efficiency. Terbium and Europium complexes demonstrate high quantum yields and high purity luminescence colors. They are therefore promising materials for photonic devices such as OLEDs, where high-intensity monochromatic emission is required.

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来源期刊

Inorganic Chemistry Communications 化学-无机化学与核化学

CiteScore

5.50

自引率

7.90%

发文量

1013

审稿时长

53 days

期刊介绍： Launched in January 1998, Inorganic Chemistry Communications is an international journal dedicated to the rapid publication of short communications in the major areas of inorganic, organometallic and supramolecular chemistry. Topics include synthetic and reaction chemistry, kinetics and mechanisms of reactions, bioinorganic chemistry, photochemistry and the use of metal and organometallic compounds in stoichiometric and catalytic synthesis or organic compounds.