氧化铬涂层重量对包装钢三价铬涂层丝状腐蚀的影响

IF 5.6 3区 材料科学 Q1 ELECTROCHEMISTRY Electrochimica Acta Pub Date : 2025-05-20 Epub Date: 2025-02-27 DOI:10.1016/j.electacta.2025.145943
E. Bluett , J. Edy , M. Dodd , A.C.A. de Vooys , N. Wint , E. Jewell , H.N. McMurray
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引用次数: 0

摘要

本文系统地研究了用于包装钢的工业上重要的Cr(III)涂层的丝状腐蚀(FFC)的产生和扩展。FFC是在金属涂层中应用的PVB有机涂层模型中引入人工刻蚀剂而产生的。随着Cr(III)氧化膜重量的增加,FFC腐蚀面积减小。这在很大程度上是由于Cr(III)氧化物的绝缘性能。氯化物滞留在尾部导致灯丝变细。结果表明,FFC在传统的电镀铬钢(ECCS)上不会引发。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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The influence of chromium oxide coating weight on filiform corrosion of trivalent chromium coatings for packaging steel
This paper describes a systematic study into the initiation and propagation of filiform corrosion (FFC) on industrially important Cr(III) coatings applied to packaging steel. FFC was initiated by introducing an artificial scribe into a model PVB organic coating which had been applied to the metallic coatings. The FFC corroded area was shown to decrease at increased values of Cr(III) oxide coating weight. This was explained largely due to the insulating properties of Cr(III) oxide. Chloride entrapment within the tail caused filament tapering. FFC was shown not to initiate on traditional electro chromium coated steel (ECCS).
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来源期刊
Electrochimica Acta
Electrochimica Acta 工程技术-电化学
CiteScore
11.30
自引率
6.10%
发文量
1634
审稿时长
41 days
期刊介绍: Electrochimica Acta is an international journal. It is intended for the publication of both original work and reviews in the field of electrochemistry. Electrochemistry should be interpreted to mean any of the research fields covered by the Divisions of the International Society of Electrochemistry listed below, as well as emerging scientific domains covered by ISE New Topics Committee.
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