通过 C (sp2)-X 键官能化将二氧化碳固定为有用的芳香族羧酸

IF 8.8 2区化学 Q1 Chemistry Topics in Current Chemistry Pub Date : 2025-03-03 DOI:10.1007/s41061-025-00496-x

Youwen Chen, Meihua Chen, Xinyu Li, Xinhua Xu, Shuang-Feng Yin, Renhua Qiu

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引用次数: 0

摘要

二氧化碳（CO2）是一种储量丰富且易于获取的碳源。它向高附加值化学品的转型是一个有益的战略，它减少了温室气体排放，并为化学工业提供了新的原料来源。其中，芳香羧酸及其衍生物在医药、农药、材料科学等方面有着广泛的应用。因此，将C(sp2)-X （X =金属、卤化物、H、O或S）与CO2键羧基化以高效构建芳香羧酸及其衍生物是一种具有重要意义的合成策略。本文综述了通过C(sp2)-X键与CO2的羧基化构建羧酸及其衍生物的最新进展，包括2000年至2024年12月发表的文献。图形抽象

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CO2 Fixation into Useful Aromatic Carboxylic Acids via C (sp2)–X Bonds Functionalization

Carbon dioxide (CO₂) is an abundant and readily available carbon source. Its transformation into high-added-value chemicals is a beneficial strategy, which mitigates greenhouse gas emissions and provides new raw material sources for the chemical industry. Among these chemicals, the aromatic carboxylic acids and derivatives have broad applications in medicine, pesticides, and materials science. Therefore, the carboxylation of C(sp²)-X (X = metal, halide, H, O, or S) bonds with CO₂ to efficiently construct aromatic carboxylic acids and their derivatives is a synthetic strategy of significance. This review highlights the recent progress in constructing carboxylic acids and derivatives through the carboxylation of C(sp²)-X bonds with CO₂ including literature published from 2000 to December 2024.

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来源期刊

Topics in Current Chemistry 化学-化学综合

CiteScore

11.70

自引率

1.20%

发文量

审稿时长

6-12 weeks

期刊介绍： Topics in Current Chemistry provides in-depth analyses and forward-thinking perspectives on the latest advancements in chemical research. This renowned journal encompasses various domains within chemical science and their intersections with biology, medicine, physics, and materials science. Each collection within the journal aims to offer a comprehensive understanding, accessible to both academic and industrial readers, of emerging research in an area that captivates a broader scientific community. In essence, Topics in Current Chemistry illuminates cutting-edge chemical research, fosters interdisciplinary collaboration, and facilitates knowledge-sharing among diverse scientific audiences.