FeGa0.4In1.6Se4的交流电特性

N. N. Niftiyev, A. O. Dashdemirov, F. M. Mammadov, R. M. Agayeva
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摘要

研究了FeGa0.4In1.6Se4晶体的介电常数和电导率对交流电流的温度和频率依赖性。FeGa0.4In1.6Se4晶体在2 × 102 ~ 104 Hz频率范围内出现正态色散,缺陷的寿命分布服从n(τ) τ−1.75规律。随着温度的升高,介电常数实部值增大的原因是缺陷浓度的增加。实验观察到介电常数虚部随频率的单调下降表明FeGa0.4In1.6Se4晶体中存在弛豫色散。在294.5 ~ 343 K的温度范围内,频率2 × 102 ~ 106 Hz,电导率符合σ f S(0.1≤S≤1.0)定律。结果表明,这些晶体的电导率具有跳带机制。活化能由\(\log \sigma \sim \frac{{{{{10}}^{3}}}}{T}\)依赖关系确定。
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Electrical Properties of FeGa0.4In1.6Se4 at Alternating Current

The temperature and frequency dependences of the dielectric constant and electrical conductivity of FeGa0.4In1.6Se4 crystals on alternating current have been studied. In the FeGa0.4In1.6Se4 crystal, normal dispersion occurs in the frequency range 2 × 102–104 Hz, and the lifetime distribution of defects obeys the law n(τ) ~ τ−1.75. With increasing temperature, the reason for an increase in the value of the real part of the dielectric constant is an increase in the concentration of defects. The experimentally observed monotonic decrease in the imaginary part of the dielectric constant depending on frequency indicates the presence of relaxation dispersion in the FeGa0.4In1.6Se4 crystal. It has been established that, in the temperature range 294.5–343 K at frequencies 2 × 102–106 Hz, the law σ ~ f S (0.1 ≤ S ≤ 1.0) is satisfied for electrical conductivity. It was shown that the conductivity in those crystals is characterized by a band-hopping mechanism. Activation energies were determined from the \(\log \sigma \sim \frac{{{{{10}}^{3}}}}{T}\) dependencies.

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来源期刊
Surface Engineering and Applied Electrochemistry
Surface Engineering and Applied Electrochemistry Engineering-Industrial and Manufacturing Engineering
CiteScore
1.60
自引率
22.20%
发文量
54
期刊介绍: Surface Engineering and Applied Electrochemistry is a journal that publishes original and review articles on theory and applications of electroerosion and electrochemical methods for the treatment of materials; physical and chemical methods for the preparation of macro-, micro-, and nanomaterials and their properties; electrical processes in engineering, chemistry, and methods for the processing of biological products and food; and application electromagnetic fields in biological systems.
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