比较了一种新的半经验数学模型和神经网络对膜生物反应器可逆污染的描述和预测

IF 3.9 3区 工程技术 Q3 ENERGY & FUELS Chemical Engineering and Processing - Process Intensification Pub Date : 2025-06-01 Epub Date: 2025-03-06 DOI:10.1016/j.cep.2025.110256
Victorino Diez , José María Cámara , Miguel Cantera , Adrián Bonilla , Cipriano Ramos
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摘要

本文比较了一种新的半经验数学模型和神经网络对膜污染的预测能力。校准和验证包括在厌氧膜生物反应器中进行的21个重复通量步实验,8个过滤通量范围为9.8至18.9 L/m²·h,以及40小时的随机通量实验。可逆结垢的内在可变性与饼堆积是量化的。除了滤饼堆积和压缩外,该数学模型还考虑了未通过反冲洗去除的残留污垢的恢复,包括未分离颗粒和胶体的重排、初始孔隙阻塞和浓度极化。该模型预测了大范围过滤通量的可逆结垢,甚至超出了用于校准的过滤通量。随机通量实验揭示了通过直接跨膜压力检测无法检测到的污染趋势。然而,当过滤过程中有效膜面积减小时,数学模型失效。神经网络预测污垢模式独立于潜在机制,提供更广泛的操作条件下的适应性。尽管如此,对于训练数据集之外的通量范围,特别是在通量明显高于或低于训练中使用的通量范围时,它很难预测可逆污垢。本研究为提高膜生物反应器的性能提供了可逆性污染描述方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Comparing a new semi-empirical mathematical model and a neural network for the description and forecasting of reversible fouling in membrane bioreactors
This study compares the predictive capability of membrane fouling between a new semi-empirical mathematical model and a neural network. Calibration and validation involved 21 replicated flux-step experiments with 8 filtration fluxes ranging from 9.8 to 18.9 L/m²·h and 40-hour random-flux experiments conducted in an anaerobic membrane bioreactor. The inherent variability of reversible fouling linked to cake build-up was quantified.
In addition to cake build-up and compression, the mathematical model incorporates the restoration of residual fouling not removed by backwashing, including the rearrangement of non-detached particles and colloids, initial pore-blocking, and concentration polarization. The model predicts reversible fouling across a wide range of filtration fluxes, even beyond those used for calibration. Random-flux experiments revealed fouling trends undetectable via direct transmembrane pressure inspection. However, the mathematical model fails when the effective membrane area decreases during filtration.
The neural network predicts fouling patterns independently of underlying mechanisms, offering adaptability across a broader range of operating conditions. Nonetheless, it struggles to predict reversible fouling for flux ranges outside its training dataset, particularly at fluxes significantly higher or lower than those used in training.
The present study offers insight into reversible fouling description in order to enhance the performance of membrane bioreactors.
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来源期刊
CiteScore
7.80
自引率
9.30%
发文量
408
审稿时长
49 days
期刊介绍: Chemical Engineering and Processing: Process Intensification is intended for practicing researchers in industry and academia, working in the field of Process Engineering and related to the subject of Process Intensification.Articles published in the Journal demonstrate how novel discoveries, developments and theories in the field of Process Engineering and in particular Process Intensification may be used for analysis and design of innovative equipment and processing methods with substantially improved sustainability, efficiency and environmental performance.
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