含复合钾盐水雾对富氢天然气射流火焰的抑制性能及机理

IF 8.3 2区 工程技术 Q1 CHEMISTRY, PHYSICAL International Journal of Hydrogen Energy Pub Date : 2025-03-27 Epub Date: 2025-03-06 DOI:10.1016/j.ijhydene.2025.03.023
Litao Liu , Zhenmin Luo , Yong Yang , Tao Wang , Bin Su , Shangyong Zhou , Yuhuai Sheng , Pengzhi Wu , Yating Zhang , Chi-Min Shu
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引用次数: 0

摘要

当富氢天然气在静止空气中被点燃时,在储存和运输过程中发生气体燃料泄漏,可能引起非预混射流火灾。细水雾系统在完全解决灭火效率挑战和与富氢天然气火灾相关的环境污染问题方面存在局限性。因此,有必要采用含钾复合盐水雾来减轻富氢天然气的泄漏风险。设计并进行了模拟实验,对含钾复合盐水雾的抑制性能进行了评价。喷嘴直径(3.15、4.0、4.94、5.65、6.0 mm)、体积流量(10、20、30、40、50、60 L/min)和喷雾压力(0.2、0.3、0.4 MPa)为变量。分析了含钾复合盐水雾的特征参数,评价了含钾复合盐水雾的可行性和有效性。通过PIV结合含钾复合盐水雾和富氢天然气射流火焰的流场,揭示、分析和阐明了气雾相互作用的竞争行为和定量关系。结果表明,该喷嘴在高喷压条件下具有较高的灭火效果。在喷雾压力抑制下,火焰高度随喷雾压力的增大而减小。综上所述,提出了基于气喷动量比的泄漏气体抑制预测模型。为了阐明含钾复合盐细水雾对富氢天然气射流火焰的抑制机理,建立了含KOH气体的简化反应动力学机制。研究结果对优化含水雾添加剂体系以抑制此类应用中的气体泄漏具有重要的参考价值。所提出的模型和机理可以为建立更准确、更高效的燃烧模型提供有价值的信息,从而提高工业过程的安全性和适用性。
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Suppression performance and mechanism of water mist containing compound potassium salts on hydrogen-enriched natural gas jet flame
A non-premixed jet fire could be caused when a gaseous fuel leakage occurs during the storage and transport of hydrogen-enriched natural gas when the fuel is ignited in still air. Water mist systems exhibit limitations in fully addressing both the fire suppression efficiency challenges and environmental contamination concerns associated with hydrogen-enriched natural gas fires. Therefore, it is necessary to mitigate the risk of hydrogen-enriched natural gas leakage by using water mist containing potassium compound salt. Simulated experiments were designed and conducted to evaluate the suppression performance of water mist containing potassium compound salt. The diameter of the nozzle (3.15, 4.0, 4.94, 5.65, and 6.0 mm), the volume flow rates (10, 20, 30, 40, 50, and 60 L/min), and the spray pressure (0.2, 0.3, and 0.4 MPa) were the variables. The characteristic parameters of the water mist containing potassium compound salt were analyzed to evaluate the feasibility and effectiveness of water mist containing potassium compound salt. Combining the flow field of water mist containing potassium compound salt and hydrogen-enriched natural gas jet flame via PIV, the competitive behavior and quantitative relationship of the gas-spray interaction was revealed, analyzed, and elucidated. The results show that the nozzle has high fire extinguishing effectiveness under high spray pressure conditions. Furthermore, the flame height under spray pressure suppression was shown to decrease with the increase in spray pressure. To sum up, a prediction model for leakage gas suppression is proposed based upon the gas-spray momentum ratio. A simplified reaction kinetic mechanism containing gaseous KOH was constructed to elucidate the suppression mechanism of hydrogen-enriched natural gas jet flame by fine water mist containing potassium compound salt. The research results have vital reference value for optimizing water mist-containing additions systems to suppress gas leakage in such applications. The proposed model and mechanism can provide valuable information to develop more accurate and efficient combustion models, thus improving the safety and applicability of industrial processes.
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来源期刊
International Journal of Hydrogen Energy
International Journal of Hydrogen Energy 工程技术-环境科学
CiteScore
13.50
自引率
25.00%
发文量
3502
审稿时长
60 days
期刊介绍: The objective of the International Journal of Hydrogen Energy is to facilitate the exchange of new ideas, technological advancements, and research findings in the field of Hydrogen Energy among scientists and engineers worldwide. This journal showcases original research, both analytical and experimental, covering various aspects of Hydrogen Energy. These include production, storage, transmission, utilization, enabling technologies, environmental impact, economic considerations, and global perspectives on hydrogen and its carriers such as NH3, CH4, alcohols, etc. The utilization aspect encompasses various methods such as thermochemical (combustion), photochemical, electrochemical (fuel cells), and nuclear conversion of hydrogen, hydrogen isotopes, and hydrogen carriers into thermal, mechanical, and electrical energies. The applications of these energies can be found in transportation (including aerospace), industrial, commercial, and residential sectors.
期刊最新文献
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