{"title":"高效析氧反应的镍锚定纳米纤维V2O5电催化剂","authors":"Rajangam Vinodh, Bruno G. Pollet","doi":"10.1016/j.ijhydene.2025.02.485","DOIUrl":null,"url":null,"abstract":"<div><div>Creating affordable and efficient catalyst for water splitting is essential for sustainable hydrogen production. This study presents a nickel-doped vanadium pentoxide (Ni–V<sub>2</sub>O<sub>5</sub>) electrocatalyst synthesized via a hydrothermal method, demonstrating enhanced oxygen evolution reaction (OER) activity. Comprehensive characterization reveals that Ni incorporation into V<sub>2</sub>O<sub>5</sub> enhances conductivity and increases active sites, contributing to improved catalytic performance. Electrochemical analyses, such as linear sweep voltammetry (LSV), Tafel slope measurements, and electrochemical impedance spectroscopy (EIS), demonstrate the superior performance of Ni–V<sub>2</sub>O<sub>5</sub> compared to undoped V<sub>2</sub>O<sub>5</sub>. The Ni–V<sub>2</sub>O<sub>5</sub> electrocatalyst achieves a low overpotential of 309 mV at +20 mA cm<sup>−2</sup> and a Tafel slope of 24 mV dec<sup>−1</sup>, underscoring its promise as a robust electrocatalyst for practical water splitting applications.</div></div>","PeriodicalId":337,"journal":{"name":"International Journal of Hydrogen Energy","volume":"113 ","pages":"Pages 395-405"},"PeriodicalIF":8.3000,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Facile and cost-effective nickel-anchored nanofibril V2O5 electrocatalyst for efficient oxygen evolution reaction\",\"authors\":\"Rajangam Vinodh, Bruno G. Pollet\",\"doi\":\"10.1016/j.ijhydene.2025.02.485\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Creating affordable and efficient catalyst for water splitting is essential for sustainable hydrogen production. This study presents a nickel-doped vanadium pentoxide (Ni–V<sub>2</sub>O<sub>5</sub>) electrocatalyst synthesized via a hydrothermal method, demonstrating enhanced oxygen evolution reaction (OER) activity. Comprehensive characterization reveals that Ni incorporation into V<sub>2</sub>O<sub>5</sub> enhances conductivity and increases active sites, contributing to improved catalytic performance. Electrochemical analyses, such as linear sweep voltammetry (LSV), Tafel slope measurements, and electrochemical impedance spectroscopy (EIS), demonstrate the superior performance of Ni–V<sub>2</sub>O<sub>5</sub> compared to undoped V<sub>2</sub>O<sub>5</sub>. The Ni–V<sub>2</sub>O<sub>5</sub> electrocatalyst achieves a low overpotential of 309 mV at +20 mA cm<sup>−2</sup> and a Tafel slope of 24 mV dec<sup>−1</sup>, underscoring its promise as a robust electrocatalyst for practical water splitting applications.</div></div>\",\"PeriodicalId\":337,\"journal\":{\"name\":\"International Journal of Hydrogen Energy\",\"volume\":\"113 \",\"pages\":\"Pages 395-405\"},\"PeriodicalIF\":8.3000,\"publicationDate\":\"2025-03-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Hydrogen Energy\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0360319925010778\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2025/3/5 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Hydrogen Energy","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0360319925010778","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/3/5 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
创造负担得起且高效的水分解催化剂对于可持续的氢气生产至关重要。采用水热法合成了一种镍掺杂的五氧化二钒(Ni-V2O5)电催化剂,该催化剂的析氧反应(OER)活性增强。综合表征表明,在V2O5中掺入Ni可以提高电导率,增加活性位点,从而提高催化性能。电化学分析,如线性扫描伏安法(LSV)、Tafel斜率测量和电化学阻抗谱(EIS),证明了Ni-V2O5与未掺杂的V2O5相比具有优越的性能。Ni-V2O5电催化剂在+20 mA cm−2下的过电位为309 mV, Tafel斜率为24 mV dec−1,强调了其作为实际水分解应用的强大电催化剂的前景。
Facile and cost-effective nickel-anchored nanofibril V2O5 electrocatalyst for efficient oxygen evolution reaction
Creating affordable and efficient catalyst for water splitting is essential for sustainable hydrogen production. This study presents a nickel-doped vanadium pentoxide (Ni–V2O5) electrocatalyst synthesized via a hydrothermal method, demonstrating enhanced oxygen evolution reaction (OER) activity. Comprehensive characterization reveals that Ni incorporation into V2O5 enhances conductivity and increases active sites, contributing to improved catalytic performance. Electrochemical analyses, such as linear sweep voltammetry (LSV), Tafel slope measurements, and electrochemical impedance spectroscopy (EIS), demonstrate the superior performance of Ni–V2O5 compared to undoped V2O5. The Ni–V2O5 electrocatalyst achieves a low overpotential of 309 mV at +20 mA cm−2 and a Tafel slope of 24 mV dec−1, underscoring its promise as a robust electrocatalyst for practical water splitting applications.
期刊介绍:
The objective of the International Journal of Hydrogen Energy is to facilitate the exchange of new ideas, technological advancements, and research findings in the field of Hydrogen Energy among scientists and engineers worldwide. This journal showcases original research, both analytical and experimental, covering various aspects of Hydrogen Energy. These include production, storage, transmission, utilization, enabling technologies, environmental impact, economic considerations, and global perspectives on hydrogen and its carriers such as NH3, CH4, alcohols, etc.
The utilization aspect encompasses various methods such as thermochemical (combustion), photochemical, electrochemical (fuel cells), and nuclear conversion of hydrogen, hydrogen isotopes, and hydrogen carriers into thermal, mechanical, and electrical energies. The applications of these energies can be found in transportation (including aerospace), industrial, commercial, and residential sectors.