封面专题:用远红外光谱和分子动力学模拟探测溶剂离子液体中阳离子-阴离子和阳离子-甘油三酯相互作用的竞争(chemphyscheme 5/2025)

IF 2.2 3区 化学 Q3 CHEMISTRY, PHYSICAL Chemphyschem Pub Date : 2025-03-04 DOI:10.1002/cphc.202580502
Jule Kristin Philipp, Koichi Fumino, Andreas Appelhagen, Dietmar Paschek, Ralf Ludwig
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引用次数: 0

摘要

覆盖特征说明了锂二(三氟甲烷磺酰基)亚胺([Li][NTf2])和三甘油三酯(G3)混合物中存在的接触离子和溶剂分离离子对,通常称为溶剂离子液体。在他们的研究文章(DOI: 10.1002/cphc.202400991)中,R. Ludwig及其同事讲述了他们如何使用远红外光谱来探测取决于盐浓度的阳离子-阴离子和阳离子-甘油三酯相互作用。分子动力学模拟提供了在这种有前途的电解质体系中形成的络合物的详细分子图像。
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Cover Feature: The Competition Between Cation-Anion and Cation-Triglyme Interaction in Solvate Ionic Liquids Probed by Far Infrared Spectroscopy and Molecular Dynamics Simulations (ChemPhysChem 5/2025)

The Cover Feature illustrates the contact and solvent-separated ion pairs present in mixtures of lithium bis(trifluoromethanesulfonyl)imide ([Li][NTf2]) and triglyme (G3), often called solvate ionic liquids. In their Research Article (DOI: 10.1002/cphc.202400991), R. Ludwig and co-workers relate how they used far infrared spectroscopy to probe cation–anion and cation–triglyme interactions depending on the salt concentration. Molecular dynamics simulations provided a detailed molecular picture of the complexes formed in this promising electrolyte system.

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来源期刊
Chemphyschem
Chemphyschem 化学-物理:原子、分子和化学物理
CiteScore
4.60
自引率
3.40%
发文量
425
审稿时长
1.1 months
期刊介绍: ChemPhysChem is one of the leading chemistry/physics interdisciplinary journals (ISI Impact Factor 2018: 3.077) for physical chemistry and chemical physics. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. ChemPhysChem is an international source for important primary and critical secondary information across the whole field of physical chemistry and chemical physics. It integrates this wide and flourishing field ranging from Solid State and Soft-Matter Research, Electro- and Photochemistry, Femtochemistry and Nanotechnology, Complex Systems, Single-Molecule Research, Clusters and Colloids, Catalysis and Surface Science, Biophysics and Physical Biochemistry, Atmospheric and Environmental Chemistry, and many more topics. ChemPhysChem is peer-reviewed.
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