{"title":"东印度海岸线重金属的空间分布、污染水平及风险评估","authors":"Mrunmayee Manjari Sahoo, Janaki Ballav Swain","doi":"10.1016/j.marpolbul.2025.117779","DOIUrl":null,"url":null,"abstract":"<div><div>The proposed comprehensive study was accomplished to analyze the ecological phenomenon, heavy metals occurrence, and its significance. The spatial distribution of heavy metals in the sediments such as Cadmium (Cd), Cobalt (Co), Cupper (Cu), Lead (Pb), Mercury (Hg), Nickel (Ni), Zinc (Zn), Iron (Fe), and Chromium (Cr) of the Eastern coastline of India (ECI) was evaluated across 61 sites along the 1400 km stretch of the Bay of Bengal and the Arabian Sea coastline. The heavy metal concentration was higher for Hg (0.08 μg/g) and Cd (3.44 μg/g), likely due to mining and extraction activities. Strong positive correlations (<span><math><msup><mi>R</mi><mn>2</mn></msup><mo>></mo><mn>0.5</mn><mo>,</mo><mi>p</mi><mo><</mo><mn>0.01</mn></math></span>) observed between Cd∼Fe <span><math><mfenced><mrow><msup><mi>R</mi><mn>2</mn></msup><mo>=</mo><mn>0.70</mn></mrow></mfenced></math></span>, Cd∼-Cr <span><math><mfenced><mrow><msup><mi>R</mi><mn>2</mn></msup><mo>=</mo><mn>0.68</mn></mrow></mfenced></math></span>, Co∼Zn <span><math><mfenced><mrow><msup><mi>R</mi><mn>2</mn></msup><mo>=</mo><mn>0.79</mn></mrow></mfenced></math></span>, Cu∼Ni <span><math><mfenced><mrow><msup><mi>R</mi><mn>2</mn></msup><mo>=</mo><mn>0.73</mn></mrow></mfenced></math></span> suggesting co-miming sources while negative correlations Ni∼Cr <span><math><mfenced><mrow><msup><mi>R</mi><mn>2</mn></msup><mo>=</mo><mo>−</mo><mn>0.50</mn></mrow></mfenced></math></span>, Ni∼Pb <span><math><mfenced><mrow><msup><mi>R</mi><mn>2</mn></msup><mo>=</mo><mo>−</mo><mn>0.56</mn></mrow></mfenced></math></span>, Cu∼Pb <span><math><mfenced><mrow><msup><mi>R</mi><mn>2</mn></msup><mo>=</mo><mo>−</mo><mn>0.58</mn></mrow></mfenced></math></span> indicate the separation of these metals in sediments due to geochemical conditions and tailing disposal. The heavy metals, Co, Cu, Pb, Ni, Fe, and Cr were under the concentrations proposed by sediment quality guidelines (SQGs). It indicated there is fewer immediate effects of heavy metals, however, even at low levels metals like Hg, Cd, and Pb can cause chronic exposure effects, bioaccumulation and subclinical health impacts over time. The stations of Utkal (UC 14–UC 18) and Coromandel (CC 8–CC 11) coastline act as shipping ports and are involved in mining activities and recorded geological weathering of rocks in these areas, compared to other sampling locations along Utkal, Andhra and Coromandel coastline.</div></div>","PeriodicalId":18215,"journal":{"name":"Marine pollution bulletin","volume":"214 ","pages":"Article 117779"},"PeriodicalIF":4.9000,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Spatial distribution, contamination levels, and risk assessment of heavy metals along the Eastern India coastline\",\"authors\":\"Mrunmayee Manjari Sahoo, Janaki Ballav Swain\",\"doi\":\"10.1016/j.marpolbul.2025.117779\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The proposed comprehensive study was accomplished to analyze the ecological phenomenon, heavy metals occurrence, and its significance. The spatial distribution of heavy metals in the sediments such as Cadmium (Cd), Cobalt (Co), Cupper (Cu), Lead (Pb), Mercury (Hg), Nickel (Ni), Zinc (Zn), Iron (Fe), and Chromium (Cr) of the Eastern coastline of India (ECI) was evaluated across 61 sites along the 1400 km stretch of the Bay of Bengal and the Arabian Sea coastline. The heavy metal concentration was higher for Hg (0.08 μg/g) and Cd (3.44 μg/g), likely due to mining and extraction activities. Strong positive correlations (<span><math><msup><mi>R</mi><mn>2</mn></msup><mo>></mo><mn>0.5</mn><mo>,</mo><mi>p</mi><mo><</mo><mn>0.01</mn></math></span>) observed between Cd∼Fe <span><math><mfenced><mrow><msup><mi>R</mi><mn>2</mn></msup><mo>=</mo><mn>0.70</mn></mrow></mfenced></math></span>, Cd∼-Cr <span><math><mfenced><mrow><msup><mi>R</mi><mn>2</mn></msup><mo>=</mo><mn>0.68</mn></mrow></mfenced></math></span>, Co∼Zn <span><math><mfenced><mrow><msup><mi>R</mi><mn>2</mn></msup><mo>=</mo><mn>0.79</mn></mrow></mfenced></math></span>, Cu∼Ni <span><math><mfenced><mrow><msup><mi>R</mi><mn>2</mn></msup><mo>=</mo><mn>0.73</mn></mrow></mfenced></math></span> suggesting co-miming sources while negative correlations Ni∼Cr <span><math><mfenced><mrow><msup><mi>R</mi><mn>2</mn></msup><mo>=</mo><mo>−</mo><mn>0.50</mn></mrow></mfenced></math></span>, Ni∼Pb <span><math><mfenced><mrow><msup><mi>R</mi><mn>2</mn></msup><mo>=</mo><mo>−</mo><mn>0.56</mn></mrow></mfenced></math></span>, Cu∼Pb <span><math><mfenced><mrow><msup><mi>R</mi><mn>2</mn></msup><mo>=</mo><mo>−</mo><mn>0.58</mn></mrow></mfenced></math></span> indicate the separation of these metals in sediments due to geochemical conditions and tailing disposal. The heavy metals, Co, Cu, Pb, Ni, Fe, and Cr were under the concentrations proposed by sediment quality guidelines (SQGs). It indicated there is fewer immediate effects of heavy metals, however, even at low levels metals like Hg, Cd, and Pb can cause chronic exposure effects, bioaccumulation and subclinical health impacts over time. The stations of Utkal (UC 14–UC 18) and Coromandel (CC 8–CC 11) coastline act as shipping ports and are involved in mining activities and recorded geological weathering of rocks in these areas, compared to other sampling locations along Utkal, Andhra and Coromandel coastline.</div></div>\",\"PeriodicalId\":18215,\"journal\":{\"name\":\"Marine pollution bulletin\",\"volume\":\"214 \",\"pages\":\"Article 117779\"},\"PeriodicalIF\":4.9000,\"publicationDate\":\"2025-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Marine pollution bulletin\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0025326X25002541\",\"RegionNum\":3,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2025/3/9 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q1\",\"JCRName\":\"ENVIRONMENTAL SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Marine pollution bulletin","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0025326X25002541","RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/3/9 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 0
摘要
本文对该地区的生态现象、重金属的赋存情况及其意义进行了综合分析。在孟加拉湾和阿拉伯海沿岸1400公里的61个地点,对印度东部海岸线沉积物中镉(Cd)、钴(Co)、铜(Cu)、铅(Pb)、汞(Hg)、镍(Ni)、锌(Zn)、铁(Fe)和铬(Cr)等重金属的空间分布进行了评价。重金属浓度较高的是汞(0.08 μg/g)和镉(3.44 μg/g),可能与采矿和提取活动有关。Cd ~ Fe R2=0.70, Cd ~ -Cr R2=0.68, Co ~ Zn R2=0.79, Cu ~ Ni R2=0.73提示共矿源,而Ni ~ Cr R2= - 0.50, Ni ~ Pb R2= - 0.56, Cu ~ Pb R2= - 0.58提示由于地球化学条件和尾矿处置,这些金属在沉积物中分离。重金属Co、Cu、Pb、Ni、Fe和Cr均在沉积物质量指南(SQGs)规定的浓度范围内。研究表明,重金属的直接影响较少,然而,即使是低水平的金属,如汞、镉和铅,也会随着时间的推移造成慢性接触效应、生物积累和亚临床健康影响。Utkal (UC 14-UC 18)和Coromandel (CC 8-CC 11)海岸线站作为航运港口,参与采矿活动,并记录了这些地区岩石的地质风化情况,与Utkal, Andhra和Coromandel海岸线沿线的其他采样地点进行了比较。
Spatial distribution, contamination levels, and risk assessment of heavy metals along the Eastern India coastline
The proposed comprehensive study was accomplished to analyze the ecological phenomenon, heavy metals occurrence, and its significance. The spatial distribution of heavy metals in the sediments such as Cadmium (Cd), Cobalt (Co), Cupper (Cu), Lead (Pb), Mercury (Hg), Nickel (Ni), Zinc (Zn), Iron (Fe), and Chromium (Cr) of the Eastern coastline of India (ECI) was evaluated across 61 sites along the 1400 km stretch of the Bay of Bengal and the Arabian Sea coastline. The heavy metal concentration was higher for Hg (0.08 μg/g) and Cd (3.44 μg/g), likely due to mining and extraction activities. Strong positive correlations () observed between Cd∼Fe , Cd∼-Cr , Co∼Zn , Cu∼Ni suggesting co-miming sources while negative correlations Ni∼Cr , Ni∼Pb , Cu∼Pb indicate the separation of these metals in sediments due to geochemical conditions and tailing disposal. The heavy metals, Co, Cu, Pb, Ni, Fe, and Cr were under the concentrations proposed by sediment quality guidelines (SQGs). It indicated there is fewer immediate effects of heavy metals, however, even at low levels metals like Hg, Cd, and Pb can cause chronic exposure effects, bioaccumulation and subclinical health impacts over time. The stations of Utkal (UC 14–UC 18) and Coromandel (CC 8–CC 11) coastline act as shipping ports and are involved in mining activities and recorded geological weathering of rocks in these areas, compared to other sampling locations along Utkal, Andhra and Coromandel coastline.
期刊介绍:
Marine Pollution Bulletin is concerned with the rational use of maritime and marine resources in estuaries, the seas and oceans, as well as with documenting marine pollution and introducing new forms of measurement and analysis. A wide range of topics are discussed as news, comment, reviews and research reports, not only on effluent disposal and pollution control, but also on the management, economic aspects and protection of the marine environment in general.