由分子内环化主导的聚乙二醇双丙烯酸酯均聚形成的水溶性热响应单链环化/结状聚合物。

IF 4.1 3区化学 Q2 POLYMER SCIENCE Macromolecular Rapid Communications Pub Date : 2025-03-10 DOI:10.1002/marc.202401068

Zishan Li, Jing Lyu, Yinghao Li, Rijian Song, Chunyu Zhao, Melissa Johnson, Tianyu Mao, Hongyun Tai, Wenxin Wang

{"title":"由分子内环化主导的聚乙二醇双丙烯酸酯均聚形成的水溶性热响应单链环化/结状聚合物。","authors":"Zishan Li, Jing Lyu, Yinghao Li, Rijian Song, Chunyu Zhao, Melissa Johnson, Tianyu Mao, Hongyun Tai, Wenxin Wang","doi":"10.1002/marc.202401068","DOIUrl":null,"url":null,"abstract":"A series of water-soluble, PEG-based single-chain cyclized/knotted polymers are successfully synthesized through the homopolymerization of poly(ethylene glycol) diacrylate (PEGDA) (Mn = 575 and 700 g mol−1, respectively) via enhanced intramolecular cyclization. The homopolymerization of the diacrylate macromers first proceeds through linear propagation, followed by self-cyclization. Under high monomer-to-initiator ratios (e.g., 100–500) and room temperature, cyclized polymers with high cyclized ratios of up to 70% are achieved without gelation. Notably, the cyclized poly(PEGDA575) exhibits concentration-dependent thermoresponsive properties in aqueous solutions.","PeriodicalId":205,"journal":{"name":"Macromolecular Rapid Communications","volume":"46 12","pages":""},"PeriodicalIF":4.1000,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/marc.202401068","citationCount":"0","resultStr":"{\"title\":\"Water Soluble Thermoresponsive Single-Chain Cyclized/Knotted Polymers from Intramolecular Cyclization Dominated Homopolymerization of PEG Diacrylate\",\"authors\":\"Zishan Li, Jing Lyu, Yinghao Li, Rijian Song, Chunyu Zhao, Melissa Johnson, Tianyu Mao, Hongyun Tai, Wenxin Wang\",\"doi\":\"10.1002/marc.202401068\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A series of water-soluble, PEG-based single-chain cyclized/knotted polymers are successfully synthesized through the homopolymerization of poly(ethylene glycol) diacrylate (PEGDA) (Mn = 575 and 700 g mol−1, respectively) via enhanced intramolecular cyclization. The homopolymerization of the diacrylate macromers first proceeds through linear propagation, followed by self-cyclization. Under high monomer-to-initiator ratios (e.g., 100–500) and room temperature, cyclized polymers with high cyclized ratios of up to 70% are achieved without gelation. Notably, the cyclized poly(PEGDA575) exhibits concentration-dependent thermoresponsive properties in aqueous solutions.\",\"PeriodicalId\":205,\"journal\":{\"name\":\"Macromolecular Rapid Communications\",\"volume\":\"46 12\",\"pages\":\"\"},\"PeriodicalIF\":4.1000,\"publicationDate\":\"2025-03-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/marc.202401068\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Macromolecular Rapid Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/marc.202401068\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Rapid Communications","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/marc.202401068","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}

引用次数: 0

摘要

以聚乙二醇二丙烯酸酯（PEGDA）为原料（Mn分别为575和700 g mol-1），通过增强分子内环化反应，成功地合成了一系列水溶性peg基单链环化/打结聚合物。双丙烯酸酯大分子的均聚首先通过线性传播进行，然后是自环化。在高单体与引发剂比（例如，100-500）和室温下，可以在不凝胶化的情况下获得高达70%的高环化比的环化聚合物。值得注意的是，环化聚（PEGDA575）在水溶液中表现出浓度依赖的热响应特性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

摘要图片

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Water Soluble Thermoresponsive Single-Chain Cyclized/Knotted Polymers from Intramolecular Cyclization Dominated Homopolymerization of PEG Diacrylate

A series of water-soluble, PEG-based single-chain cyclized/knotted polymers are successfully synthesized through the homopolymerization of poly(ethylene glycol) diacrylate (PEGDA) (M_n = 575 and 700 g mol⁻¹, respectively) via enhanced intramolecular cyclization. The homopolymerization of the diacrylate macromers first proceeds through linear propagation, followed by self-cyclization. Under high monomer-to-initiator ratios (e.g., 100–500) and room temperature, cyclized polymers with high cyclized ratios of up to 70% are achieved without gelation. Notably, the cyclized poly(PEGDA₅₇₅) exhibits concentration-dependent thermoresponsive properties in aqueous solutions.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Macromolecular Rapid Communications 工程技术-高分子科学

CiteScore

7.70

自引率

6.50%

发文量

477

审稿时长

1.4 months

期刊介绍： Macromolecular Rapid Communications publishes original research in polymer science, ranging from chemistry and physics of polymers to polymers in materials science and life sciences.