乳剂中液滴的局部场和变形

IF 5.2 2区 化学 Q2 CHEMISTRY, PHYSICAL Journal of Molecular Liquids Pub Date : 2025-06-01 Epub Date: 2025-03-15 DOI:10.1016/j.molliq.2025.127406
Arthur Zakinyan , Ali M. Ahmed , Daria Kononenko
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引用次数: 0

摘要

单个液滴在外加电场或磁场中的变形是一个传统的研究课题。乳化分散相液滴系统中的变形过程具有重要的应用价值,但目前对其了解甚少。这样的过程必须依赖于液滴之间的相互作用。在这项工作中,考虑了理想介电流体在电场中的乳剂或铁磁流体在磁场中的乳剂。计算机模拟和实验研究结果表明,在液滴系统上施加外场会导致液滴沿场拉伸,同时液滴形成链结构的过程较慢。在体系演化的初始阶段,极化液滴的远程相互作用对其变形程度的影响取决于分散相和分散介质的渗透率比。液滴随后形成链状结构,导致相邻液滴在链中表现出短程相互作用。这些相互作用是由液滴相互吸引引起的,导致液滴在场方向上被压缩,这降低了液滴的延伸程度,而不管液滴和介质的性质的比例如何。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Local field and deformation of droplets in emulsions
The deformation of individual liquid droplets in an applied electric or magnetic field is a traditional subject of research. Deformation processes in the system of droplets of the dispersed phase of an emulsion are of fundamental and applied interest but are currently poorly understood. Such processes must depend on the interaction of the droplets with each other. In this work, emulsions of ideal dielectric fluids in an electric field or ferrofluids in a magnetic field are considered. As a result of computer simulations and experimental studies, it is shown that the imposition of an external field on the system of droplets leads to their stretching along the field, accompanied by a slower process of formation of chain structures from droplets. At the initial stage of the system evolution, long-range interactions of polarized droplets can influence the degree of their deformation differently depending on the ratio of permeabilities of the dispersed phase and the dispersion medium. The subsequent formation of chain structures of droplets leads to the manifestation of short-range interactions of neighboring droplets in chains. These interactions, caused by the attraction of the droplets to each other, lead to the compression of the droplets in the field direction, which reduces the resulting degree of elongation of the droplets, regardless of the ratio of the properties of the droplets and the medium.
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来源期刊
Journal of Molecular Liquids
Journal of Molecular Liquids 化学-物理:原子、分子和化学物理
CiteScore
10.30
自引率
16.70%
发文量
2597
审稿时长
78 days
期刊介绍: The journal includes papers in the following areas: – Simple organic liquids and mixtures – Ionic liquids – Surfactant solutions (including micelles and vesicles) and liquid interfaces – Colloidal solutions and nanoparticles – Thermotropic and lyotropic liquid crystals – Ferrofluids – Water, aqueous solutions and other hydrogen-bonded liquids – Lubricants, polymer solutions and melts – Molten metals and salts – Phase transitions and critical phenomena in liquids and confined fluids – Self assembly in complex liquids.– Biomolecules in solution The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include: – Conventional spectroscopy (mid-IR and far-IR, Raman, NMR, etc.) – Non-linear optics and time resolved spectroscopy (psec, fsec, asec, ISRS, etc.) – Light scattering (Rayleigh, Brillouin, PCS, etc.) – Dielectric relaxation – X-ray and neutron scattering and diffraction. Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.
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