离子交换树脂与聚苯乙烯-二乙烯基苯基质的Fenton氧化降解动力学

IF 1.7 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Russian Chemical Bulletin Pub Date : 2025-03-27 DOI:10.1007/s11172-025-4528-3
M. M. Kozlova, V. F. Markov, L. N. Maskaeva, S. Santra, G. V. Zyryanov, A. Majee
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引用次数: 0

摘要

研究了用Fenton法氧化降解聚苯乙烯-二乙烯基苯为基体的废旧离子交换树脂的后处理问题。在含有铜(ii;)和铁(ii;,iii)盐的催化添加剂的H2O2溶液中,研究了该过程的动力学。电镜研究揭示了离子交换树脂在氧化分解过程中表面形貌和颗粒形状的特征变化。
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Oxidative degradation kinetics of ion-exchange resins with the polystyrene-divinylbenzene matrix using the Fenton process

The problem of reprocessing of used ion-exchange resins with a polystyrene-divinylbenzene matrix by oxidative degradation using the Fenton process is considered. The kinetics of the process was studied in the presence of 5–25% solutions of H2O2 containing catalytic additives of copper(ii;) and iron(ii;,iii) salts. Electron microscopic studies revealed characteristic changes in the surface morphology and granule shape of the ionexchange resins during oxidative decomposition.

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来源期刊
Russian Chemical Bulletin
Russian Chemical Bulletin 化学-化学综合
CiteScore
2.70
自引率
47.10%
发文量
257
审稿时长
3-8 weeks
期刊介绍: Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.
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