Renbo Fang , Di Zhang , Jing Dong , Yeqin Feng , Chengpeng Liu , Liaoyuan Yao , Yingnan Chi , Changwen Hu
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An open hollow polyoxovanadate cage based on {Nb(V5)} pentagons with size-selective encapsulation properties†
An open hollow polyoxovanadate (POV) cage, , has been successfully constructed using {Nb(V5)} pentagons as building blocks. The POV cage features a crown-ether-like {V4P4O8} opening that can selectively coordinate with Cs+ ions. Additionally, it has a hollow cavity that acts as a molecular container to accommodate size-appropriate organic molecules.
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