{"title":"桉木废生物炭:废水中氟蒽污染的绿色解决方案。","authors":"Yu Shuang Ren, Bekzat Tynybekov, Akmaral Nurmahanova, Talgat Ibragimov, Ussen Kurmanbay, Saltanat Nazarbekova, Askhat Kuatbayev, Akmaral Sartayeva, Muhammad Ilyas, Thiago Machado da Silva Acioly","doi":"10.1080/09603123.2025.2483976","DOIUrl":null,"url":null,"abstract":"<p><p>This study investigates the removal of fluoranthene (Flu) from vehicle-wash wastewater (VWW) using biochar (EWB) derived from eucalyptus wood waste. Analytical techniques such as surface area analysis (SAA), scanning electron microscopy (SEM), and fourier transform infrared spectroscopy (FT-IR) were employed to characterize the EWB. Optimal conditions for Flu adsorption (98.80%) were determined as 40 ppm initial concentration, 60 minutes contact time, pH 5, 60°C, and 0.4 g adsorbent dosage. The adsorption process was evaluated using kinetic models and isotherms, showing that Flu adsorption onto EWB follows a pseudo-second order kinetic model. The Langmuir isotherm provided the best fit for the experimental data. Thermodynamic analysis revealed that the adsorption process is exothermic and spontaneous, as indicated by the values of entropy (ΔS°), Gibbs free energy (ΔG°), and enthalpy (ΔH°). A comparative analysis with commercial adsorbents demonstrated the high efficacy of EWB in removing Flu from industrial wastewater, achieving over 98% efficiency.</p>","PeriodicalId":14039,"journal":{"name":"International Journal of Environmental Health Research","volume":" ","pages":"3309-3322"},"PeriodicalIF":2.0000,"publicationDate":"2025-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Eucalyptus wood waste biochar: a green solution for fluoranthene contamination in wastewater.\",\"authors\":\"Yu Shuang Ren, Bekzat Tynybekov, Akmaral Nurmahanova, Talgat Ibragimov, Ussen Kurmanbay, Saltanat Nazarbekova, Askhat Kuatbayev, Akmaral Sartayeva, Muhammad Ilyas, Thiago Machado da Silva Acioly\",\"doi\":\"10.1080/09603123.2025.2483976\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>This study investigates the removal of fluoranthene (Flu) from vehicle-wash wastewater (VWW) using biochar (EWB) derived from eucalyptus wood waste. Analytical techniques such as surface area analysis (SAA), scanning electron microscopy (SEM), and fourier transform infrared spectroscopy (FT-IR) were employed to characterize the EWB. Optimal conditions for Flu adsorption (98.80%) were determined as 40 ppm initial concentration, 60 minutes contact time, pH 5, 60°C, and 0.4 g adsorbent dosage. The adsorption process was evaluated using kinetic models and isotherms, showing that Flu adsorption onto EWB follows a pseudo-second order kinetic model. The Langmuir isotherm provided the best fit for the experimental data. Thermodynamic analysis revealed that the adsorption process is exothermic and spontaneous, as indicated by the values of entropy (ΔS°), Gibbs free energy (ΔG°), and enthalpy (ΔH°). A comparative analysis with commercial adsorbents demonstrated the high efficacy of EWB in removing Flu from industrial wastewater, achieving over 98% efficiency.</p>\",\"PeriodicalId\":14039,\"journal\":{\"name\":\"International Journal of Environmental Health Research\",\"volume\":\" \",\"pages\":\"3309-3322\"},\"PeriodicalIF\":2.0000,\"publicationDate\":\"2025-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Environmental Health Research\",\"FirstCategoryId\":\"3\",\"ListUrlMain\":\"https://doi.org/10.1080/09603123.2025.2483976\",\"RegionNum\":4,\"RegionCategory\":\"医学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2025/4/3 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q3\",\"JCRName\":\"ENVIRONMENTAL SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Environmental Health Research","FirstCategoryId":"3","ListUrlMain":"https://doi.org/10.1080/09603123.2025.2483976","RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/4/3 0:00:00","PubModel":"Epub","JCR":"Q3","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
Eucalyptus wood waste biochar: a green solution for fluoranthene contamination in wastewater.
This study investigates the removal of fluoranthene (Flu) from vehicle-wash wastewater (VWW) using biochar (EWB) derived from eucalyptus wood waste. Analytical techniques such as surface area analysis (SAA), scanning electron microscopy (SEM), and fourier transform infrared spectroscopy (FT-IR) were employed to characterize the EWB. Optimal conditions for Flu adsorption (98.80%) were determined as 40 ppm initial concentration, 60 minutes contact time, pH 5, 60°C, and 0.4 g adsorbent dosage. The adsorption process was evaluated using kinetic models and isotherms, showing that Flu adsorption onto EWB follows a pseudo-second order kinetic model. The Langmuir isotherm provided the best fit for the experimental data. Thermodynamic analysis revealed that the adsorption process is exothermic and spontaneous, as indicated by the values of entropy (ΔS°), Gibbs free energy (ΔG°), and enthalpy (ΔH°). A comparative analysis with commercial adsorbents demonstrated the high efficacy of EWB in removing Flu from industrial wastewater, achieving over 98% efficiency.
期刊介绍:
International Journal of Environmental Health Research ( IJEHR ) is devoted to the rapid publication of research in environmental health, acting as a link between the diverse research communities and practitioners in environmental health. Published articles encompass original research papers, technical notes and review articles. IJEHR publishes articles on all aspects of the interaction between the environment and human health. This interaction can broadly be divided into three areas: the natural environment and health – health implications and monitoring of air, water and soil pollutants and pollution and health improvements and air, water and soil quality standards; the built environment and health – occupational health and safety, exposure limits, monitoring and control of pollutants in the workplace, and standards of health; and communicable diseases – disease spread, control and prevention, food hygiene and control, and health aspects of rodents and insects. IJEHR is published in association with the International Federation of Environmental Health and includes news from the Federation of international meetings, courses and environmental health issues.