电致变色及锂离子电池用聚芳胺酮材料的制备及应用

IF 4.5 2区 化学 Q2 POLYMER SCIENCE Polymer Pub Date : 2025-05-16 Epub Date: 2025-04-08 DOI:10.1016/j.polymer.2025.128379
Huilin Shen, Qilin Wang, Yuntao Han, Shuo Yang, Yixuan Liu, Zheng Chen, Zhenhua Jiang
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摘要

对具有多种功能的电化学材料的研究正在稳步发展。通过两步 C-N 偶联程序将酮基连接到三苯胺结构上,制备出 PAEK-CzTPAs 多种功能共聚物,并将其应用于电致变色和电池领域。PAK-CzTPA 聚合物作为阴极活性材料,理论比容量为 122.9 mAh/g,在 0.2 C 电流密度下,PAK-CzTPA 阴极容量在 50 个循环后约为 90.0 mAh/g,容量保持率为 87.9%。6F-PAEK-CzTPA20 阴极在 0.1 C 电流密度下循环 50 次后达到 164.0 mAh/g,库仑效率为 85.0%,其本身作为粘合剂应用于三元(NCM811)电极。具有储能、电致变色特性和执行其他物理任务能力的材料具有广泛的潜在用途,可提高能源效率,节约大量资源,并使系统在整体上更具可持续性。
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Preparation and application of poly(arylamine ketone) materials for electrochromism and lithium-ion batteries
The investigation of electrochemical materials with multiple functions is steadily growing. By joining ketone groups to triphenylamine structures via a two-step C–N coupling procedure, PAEK-CzTPAs multiple function copolymers were prepared and used in the electrochromic and battery fields. When the PAK-CzTPA polymer is applied to the electrochromic field, the transmission change has a small attenuation even after 600 s. PAK-CzTPA polymer as cathode active material with a theoretical specific capacity of 122.9 mAh/g, PAK-CzTPA cathode capacity is about 90.0 mAh/g after 50 cycles with 87.9 % capacity retention at 0.2 C current density. 6F-PAEK-CzTPA20 cathode reaches 164.0 mAh/g at 0.1 C current density after 50 cycles with 85.0 % coulombic efficiency, which itself as binder is applied to ternary (NCM811) electrode. Materials with the ability to store energy, exhibit electrochromic characteristics and perform other physical tasks of materials with a wide range of potential uses that could increase energy efficiency, save an important quantity of resources and make the system more sustainable overall.
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来源期刊
Polymer
Polymer 化学-高分子科学
CiteScore
7.90
自引率
8.70%
发文量
959
审稿时长
32 days
期刊介绍: Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics. The main scope is covered but not limited to the following core areas: Polymer Materials Nanocomposites and hybrid nanomaterials Polymer blends, films, fibres, networks and porous materials Physical Characterization Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films Polymer Engineering Advanced multiscale processing methods Polymer Synthesis, Modification and Self-assembly Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization Technological Applications Polymers for energy generation and storage Polymer membranes for separation technology Polymers for opto- and microelectronics.
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