从银基到铜基丝网印刷SHJ太阳能电池的过渡

IF 6.3 2区 材料科学 Q2 ENERGY & FUELS Solar Energy Materials and Solar Cells Pub Date : 2025-04-09 DOI:10.1016/j.solmat.2025.113593
S. Pingel , F.M. Maarouf , N. Wengenmeyr , M. Linse , L. Folcarelli , J. Schube , S. Hoffmann , S. Tepner , J. Huyeng , A. Lorenz , F. Clement
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引用次数: 0

摘要

在这项工作中,我们展示了通过使用基于银、镀银铜或纯铜颗粒的低温浆料进行丝网印刷来减少高效硅异质结(SHJ)电池银消耗的可能性。所获得的网格手指的特点是对线和接触电阻以及印刷宽度。最有前途的浆料是银或镀银铜颗粒,可以打印35 μm窄的手指,低线电阻远低于10 Ω/cm。仿真表明,所实现的网格手指,导致非常低的银消耗。成本优化与效率优化的比较表明,最具成本效益的电池的效率要低得多。这可能会引入替代的低银或无银金属化技术。为了展示目前在丝网印刷无母线SHJ电池中节省银的可用选择,样品的特定银消耗量为7.5 mg/W,如果背面用纯铜膏实现,则甚至低于5 mg/W。在另一项测试中,银基电池具有相同的效率水平,改善了双面性,并减少了银用量(与参考相比为1/3),约为8 mg/W。
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Transition from silver-to copper-based screen printed SHJ solar cells
In this work, we demonstrate the possibility to reduce silver consumption for highly efficient silicon heterojunction (SHJ) cells by screen printing using low temperature paste based on silver, silver-coated copper or pure copper particles. The achieved grid fingers were characterized towards the line and contact resistance as well as the printed width. The most promising pastes with silver or silver-coated-copper particles allow printing of 35 μm narrow fingers with low line resistance of well below 10 Ω/cm. Simulations show that the achieved grid fingers, lead to very low silver consumption. Comparing cost to efficiency optimization shows that the most cost-effective cell has substantially lower efficiency. This might enable the introduction of alternative low silver or silver-free metallization techniques. To show the currently available options to save silver in screen printed busbarless SHJ cells, samples were produced with specific silver consumption of 7.5 mg/W and even below 5 mg/W if the rear side was realized with a pure copper paste. In another test, silver-based cells with same level of efficiency, improved bifaciality and reduced silver laydown (1/3 compared to reference) around 8 mg/W were successfully introduced into modules.
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来源期刊
Solar Energy Materials and Solar Cells
Solar Energy Materials and Solar Cells 工程技术-材料科学:综合
CiteScore
12.60
自引率
11.60%
发文量
513
审稿时长
47 days
期刊介绍: Solar Energy Materials & Solar Cells is intended as a vehicle for the dissemination of research results on materials science and technology related to photovoltaic, photothermal and photoelectrochemical solar energy conversion. Materials science is taken in the broadest possible sense and encompasses physics, chemistry, optics, materials fabrication and analysis for all types of materials.
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