间接电还原实现烯烃三/二氟甲基化的双自由基过程

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2025-04-14 Epub Date: 2025-04-10 DOI:10.1039/d5cc00744e
Zhening Jin , Yuan Shi , Zhangchi Zheng , Yuxin Ding , Weike Su , Changjun Zhang , YuanYuan Xie
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引用次数: 0

摘要

A标题是主要的标题类型,例如引言、结果和讨论、实验。由于电化学反应的高反应性,自由基中间体通常表现出很短的寿命。本研究提出了一种稳定、温和的三/二氟甲基化烯烃电化学双自由基策略。氰芳烃和菲作为双氧化还原介质的协同组合构建了高效的催化体系。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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A dual-radical process for tri/di-fluoromethylarylation of alkenes enabled by indirect electroreduction†
This study presents a stable and mild electrochemical dual-radical strategy for tri/di-fluoromethylarylation of alkenes. The synergistic combination of cyanoarene and phenanthrene as dual redox mediators constructs an efficient catalytic system.
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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