节能建筑智能电致变色窗的新型材料

IF 3.3 4区材料科学 Q3 CHEMISTRY, PHYSICAL Solid State Ionics Pub Date : 2025-04-15 DOI:10.1016/j.ssi.2025.116850

P.J. Nunes , Wojciech Zając , Katarzyna Styszko , Sónia Pereira , Elvira Fortunato , V. de Zea Bermudez , M. Fernandes

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引用次数: 0

摘要

本文采用溶胶-凝胶法合成了三种室温离子液体（1-甲基咪唑氯（[MIm]Cl）、1-乙基-3-甲基咪唑氯（[EMIm]Cl）和1-丁基-3-甲基咪唑氯（[BMIm]Cl））掺杂的新型二脲嘧啶杂化材料，并评价了它们在电致变色器件（ECDs）中作为酶解物的潜力。所开发的ECDs具有高可见光和近红外（NIR）透明度，快速开关时间，良好的显色效率和记忆效应，使我们可以预见其在节能智能电致变色窗口中的应用。

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Novel ormolytes for smart electrochromic windows for energy-efficient buildings

In this work, novel di-ureasil hybrid materials doped with three room-temperature ionic liquids (RTILs) (1-methylimidazolium chloride ([MIm]Cl), 1-ethyl-3-methylimidazolium chloride ([EMIm]Cl), and 1-butyl-3-methylimidazolium chloride ([BMIm]Cl)) are synthesized by the sol-gel method, and their potential as ormolytes in electrochromic devices (ECDs) is evaluated. The ECDs developed exhibit high visible and near-infrared (NIR) transparency, fast switching times, and good coloration efficiency and memory effect, allowing us to foresee their application in energy-efficient smart electrochromic windows.

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来源期刊

Solid State Ionics 物理-物理：凝聚态物理

CiteScore

6.10

自引率

3.10%

发文量

152

审稿时长

58 days

期刊介绍： This interdisciplinary journal is devoted to the physics, chemistry and materials science of diffusion, mass transport, and reactivity of solids. The major part of each issue is devoted to articles on: (i) physics and chemistry of defects in solids; (ii) reactions in and on solids, e.g. intercalation, corrosion, oxidation, sintering; (iii) ion transport measurements, mechanisms and theory; (iv) solid state electrochemistry; (v) ionically-electronically mixed conducting solids. Related technological applications are also included, provided their characteristics are interpreted in terms of the basic solid state properties. Review papers and relevant symposium proceedings are welcome.