离心纺丝相分离制备多孔聚乳酸纤维用于脱油

IF 4.6 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY RSC Advances Pub Date : 2025-04-15 DOI:10.1039/D4RA08727E
Kenji Kinashi, Masaki Negoro, Hoan Ngoc Doan, Phu Phong Vo, Khanh Van Thi Khuat, Wataru Sakai and Naoto Tsutsumi
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引用次数: 0

摘要

传统的分离材料由于其不可降解性而造成二次污染,因此开发环保型吸油纤维材料至关重要。采用离心纺丝和非溶剂相分离相结合的方法制备了高疏水性和超亲油性多孔聚乳酸(PLA)纤维。通过调节纺丝液中好溶剂与非溶剂的比例来控制纤维的孔隙率。系统地分析了聚乳酸纤维的形态和物理性能。在制备的样品中,由氯仿/二甲基甲酰胺(80/20 w/w)溶液纺成的PLA纤维膜具有较高的水接触角和优异的吸油能力。这些结果证明了多孔聚乳酸纤维作为环境应用的可持续材料的潜力。
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Porous polylactic acid fibers synthesized by centrifugal spinning with phase separation for oil removal application†

The development of environmentally friendly oil-absorbing fibrous materials is crucial, as conventional separation materials contribute to secondary pollution due to their nondegradability. In this study, highly hydrophobic and superoleophilic porous polylactic acid (PLA) fibers were fabricated via centrifugal spinning combined with nonsolvent-induced phase separation. The fiber porosity was controlled by adjusting the ratio of good solvents to nonsolvent in the spinning solution. The morphology and physical properties of the PLA fibers were systematically analyzed. Among the prepared samples, PLA fibrous membranes spun from a chloroform/dimethylformamide (80/20 w/w) solution exhibited a high water contact angle and superior oil absorption capacity. These results demonstrate the potential of porous PLA fibers as sustainable materials for environmental applications.

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来源期刊
RSC Advances
RSC Advances chemical sciences-
CiteScore
7.50
自引率
2.60%
发文量
3116
审稿时长
1.6 months
期刊介绍: An international, peer-reviewed journal covering all of the chemical sciences, including multidisciplinary and emerging areas. RSC Advances is a gold open access journal allowing researchers free access to research articles, and offering an affordable open access publishing option for authors around the world.
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