Alexander Mondragón-Díaz, Steven P. Kelley, Nilay Hazari and Wesley H. Bernskoetter
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A highly active sulfur based pincer ruthenium catalyst for CO2 hydrogenation†
The synthesis of a new air-stable SPS pincer ligand that supports a Ru catalyst for CO2 hydrogenation to formate is described. This rare S-donor based pincer system gives higher activity compared to related PNP supported Ru catalysts and is less dependent on Lewis acidic Li co-catalysts for achieving high turnover numbers. The SPS ligated Ru catalyst is also active for N-formylation of amines with CO2.
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ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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