Gulaim A. Seisenbaeva, Lars Kloo, Peter Agback and Vadim G. Kessler
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Polymerisation isomerism of tungsten(vi) oxomethoxide: new insights into the structure and reactivity of non-cluster metal oxoalkoxide aggregates†
Polymerization isomerism is potentially important for metal alkoxides as precursors of oxide materials. Here, we present this phenomenon for tungsten oxo-methoxide, reporting the molecular and crystal structure of its polymeric form [WO(OMe)4]∞(1), its dimeric form W2O2(OMe)8(2), and a higher extent oxo-substituted by-product of the synthesis, Li2(MeOH)6W12O29(OMe)16(3).
期刊介绍：
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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