不同螺栓组合方式对钛铝接头电偶腐蚀的研究

IF 5.6 3区 材料科学 Q1 ELECTROCHEMISTRY Electrochimica Acta Pub Date : 2025-07-10 Epub Date: 2025-04-21 DOI:10.1016/j.electacta.2025.146280
Kaihui Dong , Yingwei Song , En-Hou Han
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引用次数: 0

摘要

Ti和Al合金这两种轻质金属广泛应用于航空航天工业,在实际应用中不可避免地要连接成Ti-Al接头。装配方式对钛铝接头的电偶腐蚀行为有显著影响。通过电化学试验、有限元建模和中性盐雾验证,研究了304不锈钢和H62黄铜螺栓组合的TC18钛合金和20250铝合金接头的电腐蚀速率和“效应距离”。结果表明:与304不锈钢螺栓相比,采用H62黄铜螺栓时,阳极2050铝合金的腐蚀速率提高了约50%;这种现象是由于在电偶腐蚀过程中,阴极304不锈钢表面的钝化膜得到改善,抑制了电荷的转移,从而降低了加速效应。由于耐溶性的影响,电偶腐蚀的“影响距离”仅为5mm左右。螺栓周围2050铝合金的腐蚀主要由螺栓而不是TC18加速,而在“影响距离”范围内的其他接触区域,TC18钛合金起主要作用,加速效果主要由Ti和Al的阴极/阳极面积比决定。
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Study on the galvanic corrosion of Ti-Al joints with different bolting assembly methods
Two lightweight metals of Ti and Al alloys are widely applied in the aerospace industry, which are inevitably connected as Ti-Al joints in practical applications. The assembly method significantly influences the galvanic corrosion behavior of Ti-Al joints. The galvanic corrosion rate and “effect distance” of TC18 Ti alloy and 20,250 Al alloy joints assembled with the bolts of 304 stainless steel and H62 brass were investigated by electrochemical tests, finite element modelling (FEM), and neutral salt spray validation. The results indicate that the corrosion rate of the anode 2050 Al alloy increases by approximately 50 % when H62 brass bolts are employed compared to 304 stainless steel bolts. This phenomenon is attributed to the improvement of passivation film on the cathode 304 stainless steel during the galvanic corrosion process, which inhibits the charge transfer to reduce the acceleration effect. Due to the effect of solution resistance, the “effect distance” of galvanic corrosion is only approximately 5 mm. The corrosion of 2050 Al alloy around the bolts is mainly accelerated by the bolts instead of TC18, whereas other contact regions within the “effect distance” range, the TC18 Ti alloy plays a main role, and the acceleration effect is mainly determined by the cathode/anode area ratios of Ti and Al.
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来源期刊
Electrochimica Acta
Electrochimica Acta 工程技术-电化学
CiteScore
11.30
自引率
6.10%
发文量
1634
审稿时长
41 days
期刊介绍: Electrochimica Acta is an international journal. It is intended for the publication of both original work and reviews in the field of electrochemistry. Electrochemistry should be interpreted to mean any of the research fields covered by the Divisions of the International Society of Electrochemistry listed below, as well as emerging scientific domains covered by ISE New Topics Committee.
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