热处理方法增强热塑性钻孔CF/PEEK复合层压板的拉伸性能

IF 3.1 3区 化学 Q2 POLYMER SCIENCE Journal of Applied Polymer Science Pub Date : 2025-02-26 DOI:10.1002/app.56912
Wenhui Yuan, Chang Liu, Tao Yang, Yu Du, Sinan Liu
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引用次数: 0

摘要

热塑性碳纤维增强聚醚醚酮(CF/PEEK)复合材料以其独特的可回收性和可重复使用性在航空航天领域具有广阔的应用前景。提出了一种基于结晶度控制的提高CF/PEEK复合材料层合板拉伸性能的热处理方法。热塑性CF/PEEK复合材料的结晶度是决定其力学性能的关键因素。CF/PEEK复合材料的非等温结晶动力学表明,在冷却速度为2℃/min时,该复合材料的结晶时间最长,结晶度最高,为热处理的炉冷方式选择提供了依据。在320℃下进行复合热处理,可使层压板的拉伸载荷提高25.68%。采用数字图像相关技术跟踪CF/PEEK样品在拉伸过程中的变形和应变分布。对钻孔层合板拉伸破坏模式的研究表明,纤维断裂和层内破坏是主要机制,热处理有效地增强了聚合物基体,从而提高了层合板的整体拉伸性能。该研究为在各种工业应用中优化钻孔热塑性复合材料提供了有价值的见解和实践指导。
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Enhanced Tensile Properties of Drilled Thermoplastic CF/PEEK Composite Laminate Using Heat Treatment Methods

Thermoplastic carbon fiber reinforced polyetheretherketone (CF/PEEK) composite materials have broad application prospects in the aerospace field due to their unique recyclability and reusability. This paper proposes a novel heat treatment method aimed at enhancing the tensile properties of drilled CF/PEEK composite laminates based on crystallinity control. The crystallinity of the thermoplastic CF/PEEK composite plays a pivotal role in determining its mechanical properties. The nonisothermal crystallization kinetics of the CF/PEEK composite indicate that the composites have the longest crystallization time and the highest crystallinity at a cooling rate of 2°C/min, which provides a basis for the selection of furnace cooling for heat treatment. The combined heat treatment conducted at 320°C can increase the tensile load of the laminate by up to 25.68%. Digital image correlation technology is used to track the deformation and strain distribution in drilled CF/PEEK samples during the tensile process. Investigation of the tensile failure modes of the drilled laminate indicates fiber fracture and intralaminar failure as the primary mechanisms, with heat treatment effectively strengthening the polymer matrix and, consequently, enhancing the overall tensile performance of the laminates. This research provides valuable insights and practical guidance for optimizing the drilled thermoplastic composites in various industrial applications.

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来源期刊
Journal of Applied Polymer Science
Journal of Applied Polymer Science 化学-高分子科学
CiteScore
5.70
自引率
10.00%
发文量
1280
审稿时长
2.7 months
期刊介绍: The Journal of Applied Polymer Science is the largest peer-reviewed publication in polymers, #3 by total citations, and features results with real-world impact on membranes, polysaccharides, and much more.
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