{"title":"高效微波吸收C/CoNi复合材料的可扩展制备","authors":"Hong Zhang , Meishan Li , Xiaohai Li","doi":"10.1016/j.diamond.2025.112355","DOIUrl":null,"url":null,"abstract":"<div><div>The increasing demand for high-efficiency microwave absorbing materials, driven by the rapid advancement of communication technologies such as 5G and 6G, necessitates the development of scalable and cost-effective solutions. In this study, biomass-derived carbon has recently gained significant attention due to its sustainability and potential for large-scale production. However, achieving both lightweight properties and strong, broadband absorption performance remains a challenge. To address these challenges, we employed a simple hydrothermal synthesis method to deposit magnetic particles onto the surfaces of biomass-derived carbon, thereby producing C/CoNi composites with excellent electromagnetic wave absorption (EWA) characteristics. The uniform dispersion of magnetic particles on the biomass carbon surface enhances the interfacial polarization effect, while the introduction of CoNi significantly enhances the surface conductivity of the C/CoNi composites, thereby improving their microwave absorption performance. Consequently, these composites demonstrate outstanding EWA properties, characterized by thin-layer structures, lightweight design, wide frequency bandwidth, and high absorption efficiency. When combined with paraffin wax (30 wt% loading), the composite exhibits a minimum reflection loss (RL<sub>min</sub>) of −54.59 dB and an effective absorption bandwidth (EAB) of 3.96 GHz. This work demonstrates the feasibility of using biomass-derived carbon for the mass production of microwave absorbers, offering a scalable and efficient solution for the development of functional materials for EWA.</div></div>","PeriodicalId":11266,"journal":{"name":"Diamond and Related Materials","volume":"155 ","pages":"Article 112355"},"PeriodicalIF":5.1000,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Scalable fabrication of C/CoNi composites for high-efficiency microwave absorption\",\"authors\":\"Hong Zhang , Meishan Li , Xiaohai Li\",\"doi\":\"10.1016/j.diamond.2025.112355\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The increasing demand for high-efficiency microwave absorbing materials, driven by the rapid advancement of communication technologies such as 5G and 6G, necessitates the development of scalable and cost-effective solutions. In this study, biomass-derived carbon has recently gained significant attention due to its sustainability and potential for large-scale production. However, achieving both lightweight properties and strong, broadband absorption performance remains a challenge. To address these challenges, we employed a simple hydrothermal synthesis method to deposit magnetic particles onto the surfaces of biomass-derived carbon, thereby producing C/CoNi composites with excellent electromagnetic wave absorption (EWA) characteristics. The uniform dispersion of magnetic particles on the biomass carbon surface enhances the interfacial polarization effect, while the introduction of CoNi significantly enhances the surface conductivity of the C/CoNi composites, thereby improving their microwave absorption performance. Consequently, these composites demonstrate outstanding EWA properties, characterized by thin-layer structures, lightweight design, wide frequency bandwidth, and high absorption efficiency. When combined with paraffin wax (30 wt% loading), the composite exhibits a minimum reflection loss (RL<sub>min</sub>) of −54.59 dB and an effective absorption bandwidth (EAB) of 3.96 GHz. This work demonstrates the feasibility of using biomass-derived carbon for the mass production of microwave absorbers, offering a scalable and efficient solution for the development of functional materials for EWA.</div></div>\",\"PeriodicalId\":11266,\"journal\":{\"name\":\"Diamond and Related Materials\",\"volume\":\"155 \",\"pages\":\"Article 112355\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2025-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Diamond and Related Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0925963525004121\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2025/4/20 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, COATINGS & FILMS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Diamond and Related Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0925963525004121","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/4/20 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"MATERIALS SCIENCE, COATINGS & FILMS","Score":null,"Total":0}
Scalable fabrication of C/CoNi composites for high-efficiency microwave absorption
The increasing demand for high-efficiency microwave absorbing materials, driven by the rapid advancement of communication technologies such as 5G and 6G, necessitates the development of scalable and cost-effective solutions. In this study, biomass-derived carbon has recently gained significant attention due to its sustainability and potential for large-scale production. However, achieving both lightweight properties and strong, broadband absorption performance remains a challenge. To address these challenges, we employed a simple hydrothermal synthesis method to deposit magnetic particles onto the surfaces of biomass-derived carbon, thereby producing C/CoNi composites with excellent electromagnetic wave absorption (EWA) characteristics. The uniform dispersion of magnetic particles on the biomass carbon surface enhances the interfacial polarization effect, while the introduction of CoNi significantly enhances the surface conductivity of the C/CoNi composites, thereby improving their microwave absorption performance. Consequently, these composites demonstrate outstanding EWA properties, characterized by thin-layer structures, lightweight design, wide frequency bandwidth, and high absorption efficiency. When combined with paraffin wax (30 wt% loading), the composite exhibits a minimum reflection loss (RLmin) of −54.59 dB and an effective absorption bandwidth (EAB) of 3.96 GHz. This work demonstrates the feasibility of using biomass-derived carbon for the mass production of microwave absorbers, offering a scalable and efficient solution for the development of functional materials for EWA.
期刊介绍:
DRM is a leading international journal that publishes new fundamental and applied research on all forms of diamond, the integration of diamond with other advanced materials and development of technologies exploiting diamond. The synthesis, characterization and processing of single crystal diamond, polycrystalline films, nanodiamond powders and heterostructures with other advanced materials are encouraged topics for technical and review articles. In addition to diamond, the journal publishes manuscripts on the synthesis, characterization and application of other related materials including diamond-like carbons, carbon nanotubes, graphene, and boron and carbon nitrides. Articles are sought on the chemical functionalization of diamond and related materials as well as their use in electrochemistry, energy storage and conversion, chemical and biological sensing, imaging, thermal management, photonic and quantum applications, electron emission and electronic devices.
The International Conference on Diamond and Carbon Materials has evolved into the largest and most well attended forum in the field of diamond, providing a forum to showcase the latest results in the science and technology of diamond and other carbon materials such as carbon nanotubes, graphene, and diamond-like carbon. Run annually in association with Diamond and Related Materials the conference provides junior and established researchers the opportunity to exchange the latest results ranging from fundamental physical and chemical concepts to applied research focusing on the next generation carbon-based devices.