高效微波吸收C/CoNi复合材料的可扩展制备

IF 5.1 3区 材料科学 Q2 MATERIALS SCIENCE, COATINGS & FILMS Diamond and Related Materials Pub Date : 2025-05-01 Epub Date: 2025-04-20 DOI:10.1016/j.diamond.2025.112355
Hong Zhang , Meishan Li , Xiaohai Li
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引用次数: 0

摘要

在5G和6G等通信技术快速发展的推动下,对高效微波吸收材料的需求不断增长,需要开发可扩展且具有成本效益的解决方案。在这项研究中,由于其可持续性和大规模生产的潜力,生物质衍生碳最近受到了极大的关注。然而,实现轻量化和强大的宽带吸收性能仍然是一个挑战。为了解决这些问题,我们采用了一种简单的水热合成方法,将磁性颗粒沉积在生物质衍生碳的表面,从而生产出具有优异电磁波吸收(EWA)特性的C/CoNi复合材料。磁性颗粒在生物质碳表面的均匀分散增强了界面极化效应,而CoNi的引入显著增强了C/CoNi复合材料的表面导电性,从而提高了其微波吸收性能。因此,这些复合材料表现出优异的EWA性能,具有薄层结构、轻量化设计、宽频率带宽和高吸收效率的特点。当与石蜡(30wt %负载)复合时,该复合材料的最小反射损耗(RLmin)为−54.59 dB,有效吸收带宽(EAB)为3.96 GHz。这项工作证明了使用生物质衍生碳大规模生产微波吸收器的可行性,为EWA功能材料的开发提供了一个可扩展和高效的解决方案。
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Scalable fabrication of C/CoNi composites for high-efficiency microwave absorption
The increasing demand for high-efficiency microwave absorbing materials, driven by the rapid advancement of communication technologies such as 5G and 6G, necessitates the development of scalable and cost-effective solutions. In this study, biomass-derived carbon has recently gained significant attention due to its sustainability and potential for large-scale production. However, achieving both lightweight properties and strong, broadband absorption performance remains a challenge. To address these challenges, we employed a simple hydrothermal synthesis method to deposit magnetic particles onto the surfaces of biomass-derived carbon, thereby producing C/CoNi composites with excellent electromagnetic wave absorption (EWA) characteristics. The uniform dispersion of magnetic particles on the biomass carbon surface enhances the interfacial polarization effect, while the introduction of CoNi significantly enhances the surface conductivity of the C/CoNi composites, thereby improving their microwave absorption performance. Consequently, these composites demonstrate outstanding EWA properties, characterized by thin-layer structures, lightweight design, wide frequency bandwidth, and high absorption efficiency. When combined with paraffin wax (30 wt% loading), the composite exhibits a minimum reflection loss (RLmin) of −54.59 dB and an effective absorption bandwidth (EAB) of 3.96 GHz. This work demonstrates the feasibility of using biomass-derived carbon for the mass production of microwave absorbers, offering a scalable and efficient solution for the development of functional materials for EWA.
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来源期刊
Diamond and Related Materials
Diamond and Related Materials 工程技术-材料科学:综合
CiteScore
6.00
自引率
14.60%
发文量
702
审稿时长
2.1 months
期刊介绍: DRM is a leading international journal that publishes new fundamental and applied research on all forms of diamond, the integration of diamond with other advanced materials and development of technologies exploiting diamond. The synthesis, characterization and processing of single crystal diamond, polycrystalline films, nanodiamond powders and heterostructures with other advanced materials are encouraged topics for technical and review articles. In addition to diamond, the journal publishes manuscripts on the synthesis, characterization and application of other related materials including diamond-like carbons, carbon nanotubes, graphene, and boron and carbon nitrides. Articles are sought on the chemical functionalization of diamond and related materials as well as their use in electrochemistry, energy storage and conversion, chemical and biological sensing, imaging, thermal management, photonic and quantum applications, electron emission and electronic devices. The International Conference on Diamond and Carbon Materials has evolved into the largest and most well attended forum in the field of diamond, providing a forum to showcase the latest results in the science and technology of diamond and other carbon materials such as carbon nanotubes, graphene, and diamond-like carbon. Run annually in association with Diamond and Related Materials the conference provides junior and established researchers the opportunity to exchange the latest results ranging from fundamental physical and chemical concepts to applied research focusing on the next generation carbon-based devices.
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