{"title":"核黄素中性光解的中间体。","authors":"M S Jorns, P Hemmerich","doi":"10.1515/znb-1972-0910","DOIUrl":null,"url":null,"abstract":"The formation of a species with an absorption maximum around 410 nm, observed during the neutral photolysis of 10-(2'-hydroxyalkyl) flavins by earlier authors, is shown to depend on the presence of divalent anions. The structure of this new type of compounds is presented and a possible mechanism for the reaction is discussed.","PeriodicalId":78857,"journal":{"name":"Zeitschrift fur Naturforschung. Teil B. Anorganische Chemie, organische Chemie, Biochemie, Biophysik, Biologie","volume":"27 9","pages":"1040-4"},"PeriodicalIF":0.0000,"publicationDate":"1972-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/znb-1972-0910","citationCount":"7","resultStr":"{\"title\":\"Intermediates in the neutral photolysis of riboflavin.\",\"authors\":\"M S Jorns, P Hemmerich\",\"doi\":\"10.1515/znb-1972-0910\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The formation of a species with an absorption maximum around 410 nm, observed during the neutral photolysis of 10-(2'-hydroxyalkyl) flavins by earlier authors, is shown to depend on the presence of divalent anions. The structure of this new type of compounds is presented and a possible mechanism for the reaction is discussed.\",\"PeriodicalId\":78857,\"journal\":{\"name\":\"Zeitschrift fur Naturforschung. Teil B. Anorganische Chemie, organische Chemie, Biochemie, Biophysik, Biologie\",\"volume\":\"27 9\",\"pages\":\"1040-4\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1972-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1515/znb-1972-0910\",\"citationCount\":\"7\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Zeitschrift fur Naturforschung. Teil B. Anorganische Chemie, organische Chemie, Biochemie, Biophysik, Biologie\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1515/znb-1972-0910\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift fur Naturforschung. Teil B. Anorganische Chemie, organische Chemie, Biochemie, Biophysik, Biologie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/znb-1972-0910","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Intermediates in the neutral photolysis of riboflavin.
The formation of a species with an absorption maximum around 410 nm, observed during the neutral photolysis of 10-(2'-hydroxyalkyl) flavins by earlier authors, is shown to depend on the presence of divalent anions. The structure of this new type of compounds is presented and a possible mechanism for the reaction is discussed.
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