{"title":"巴尔米拉仁壳不同活性炭去除酚类化合物效果的比较研究","authors":"Ganeshalingm Sashikesh , Periyasamy Anushkkaran , Yadhavan Praveena , Manjceevan Arumukham , Velauthamurty Kugamoorthy , Vignarooban Kandasamy","doi":"10.1016/j.crgsc.2023.100355","DOIUrl":null,"url":null,"abstract":"<div><p>Phenol is one of the most prevalent contaminants discovered in water bodies. The adsorption process is gaining popularity as a viable method of removing phenolic chemicals from contaminated aquatic resources. The elimination of phenolic chemicals using Palmyra kernel shell activated charcoal has been extensively investigated. The removal effectiveness of Palmyra kernel shell charcoal was calculated using physically, chemically (<span><math><mrow><msub><mi>H</mi><mn>3</mn></msub><mi>P</mi><msub><mi>O</mi><mn>4</mn></msub></mrow></math></span> and <span><math><mrow><mi>N</mi><mi>a</mi><mi>O</mi><mi>H</mi></mrow></math></span>) and magnetically activated Palmyra kernel shell charcoal for various amounts of phenolic components and varying adsorption durations. According to this research study, physically activated charcoal has a much higher removal efficiency than other activated charcoal. These findings show that physically activated charcoal is easily used to remove phenolic compounds from polluted water resources. Adsorption kinetics were discovered to follow a pseudo-second-order kinetic model. Freundlich, Langmuir, and Temkin isotherm models were used to interpret the experimental results. Several kinetic formulas were utilized to evaluate the adsorption kinetics of phenolic compounds using various activated charcoals derived from Palmyra kernel shells. The experimental results are consistent with the Freundlich isotherm model. All of the activated and non-activated Palmyra kernel shells absorbed the phenolic chemicals, and the value of <span><math><mrow><mn>1</mn><mo>/</mo><mi>n</mi></mrow></math></span> was found to be between <span><math><mrow><mn>0.692</mn></mrow></math></span> to <span><math><mrow><mn>0.869</mn></mrow></math></span>. Scanning Electron Microscopy (SEM) is a technique used to characterize the surface morphology of adsorbents before and after adsorption. FTIR analyses confirmed the presence of phenolic compound functional groups on the adsorbents.</p></div>","PeriodicalId":296,"journal":{"name":"Current Research in Green and Sustainable Chemistry","volume":"6 ","pages":"Article 100355"},"PeriodicalIF":0.0000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A comparison study of the efficacy of different activated charcoals derived from Palmyra kernel shell in removing phenolic compounds\",\"authors\":\"Ganeshalingm Sashikesh , Periyasamy Anushkkaran , Yadhavan Praveena , Manjceevan Arumukham , Velauthamurty Kugamoorthy , Vignarooban Kandasamy\",\"doi\":\"10.1016/j.crgsc.2023.100355\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Phenol is one of the most prevalent contaminants discovered in water bodies. The adsorption process is gaining popularity as a viable method of removing phenolic chemicals from contaminated aquatic resources. The elimination of phenolic chemicals using Palmyra kernel shell activated charcoal has been extensively investigated. The removal effectiveness of Palmyra kernel shell charcoal was calculated using physically, chemically (<span><math><mrow><msub><mi>H</mi><mn>3</mn></msub><mi>P</mi><msub><mi>O</mi><mn>4</mn></msub></mrow></math></span> and <span><math><mrow><mi>N</mi><mi>a</mi><mi>O</mi><mi>H</mi></mrow></math></span>) and magnetically activated Palmyra kernel shell charcoal for various amounts of phenolic components and varying adsorption durations. According to this research study, physically activated charcoal has a much higher removal efficiency than other activated charcoal. These findings show that physically activated charcoal is easily used to remove phenolic compounds from polluted water resources. Adsorption kinetics were discovered to follow a pseudo-second-order kinetic model. Freundlich, Langmuir, and Temkin isotherm models were used to interpret the experimental results. Several kinetic formulas were utilized to evaluate the adsorption kinetics of phenolic compounds using various activated charcoals derived from Palmyra kernel shells. The experimental results are consistent with the Freundlich isotherm model. All of the activated and non-activated Palmyra kernel shells absorbed the phenolic chemicals, and the value of <span><math><mrow><mn>1</mn><mo>/</mo><mi>n</mi></mrow></math></span> was found to be between <span><math><mrow><mn>0.692</mn></mrow></math></span> to <span><math><mrow><mn>0.869</mn></mrow></math></span>. Scanning Electron Microscopy (SEM) is a technique used to characterize the surface morphology of adsorbents before and after adsorption. FTIR analyses confirmed the presence of phenolic compound functional groups on the adsorbents.</p></div>\",\"PeriodicalId\":296,\"journal\":{\"name\":\"Current Research in Green and Sustainable Chemistry\",\"volume\":\"6 \",\"pages\":\"Article 100355\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Current Research in Green and Sustainable Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666086523000012\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"Materials Science\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Current Research in Green and Sustainable Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666086523000012","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Materials Science","Score":null,"Total":0}
A comparison study of the efficacy of different activated charcoals derived from Palmyra kernel shell in removing phenolic compounds
Phenol is one of the most prevalent contaminants discovered in water bodies. The adsorption process is gaining popularity as a viable method of removing phenolic chemicals from contaminated aquatic resources. The elimination of phenolic chemicals using Palmyra kernel shell activated charcoal has been extensively investigated. The removal effectiveness of Palmyra kernel shell charcoal was calculated using physically, chemically ( and ) and magnetically activated Palmyra kernel shell charcoal for various amounts of phenolic components and varying adsorption durations. According to this research study, physically activated charcoal has a much higher removal efficiency than other activated charcoal. These findings show that physically activated charcoal is easily used to remove phenolic compounds from polluted water resources. Adsorption kinetics were discovered to follow a pseudo-second-order kinetic model. Freundlich, Langmuir, and Temkin isotherm models were used to interpret the experimental results. Several kinetic formulas were utilized to evaluate the adsorption kinetics of phenolic compounds using various activated charcoals derived from Palmyra kernel shells. The experimental results are consistent with the Freundlich isotherm model. All of the activated and non-activated Palmyra kernel shells absorbed the phenolic chemicals, and the value of was found to be between to . Scanning Electron Microscopy (SEM) is a technique used to characterize the surface morphology of adsorbents before and after adsorption. FTIR analyses confirmed the presence of phenolic compound functional groups on the adsorbents.