Bingcheng Lin , Guorui Liu , Guanglong Wu , Changzhi Chen , Yong Liang , Pu Wang , Jianping Guo , Lili Yang , Rong Jin , Yuxiang Sun , Minghui Zheng
{"title":"铜二次冶炼过程中PBDD/F、溴化多环芳烃和PBDE同系物形成特征的变化","authors":"Bingcheng Lin , Guorui Liu , Guanglong Wu , Changzhi Chen , Yong Liang , Pu Wang , Jianping Guo , Lili Yang , Rong Jin , Yuxiang Sun , Minghui Zheng","doi":"10.1016/j.jhazmat.2022.129602","DOIUrl":null,"url":null,"abstract":"<div><p>Simultaneous determination of 58 congeners of polybrominated dibenzo-<em>p</em><span>-dioxins and dibenzofurans<span><span> (PBDD/Fs), brominated polycyclic aromatic hydrocarbons (Br-PAHs), and polybrominated diphenyl ethers (PBDEs) from multiple stages of industrial-scale secondary copper smelting plants was conducted with the aim of understanding their variations and control. In addition to the historical manufacture of PBDEs as brominated </span>flame retardants, this study confirmed that PBDEs can be unintentionally produced and released from the secondary copper industry. The average mass emission factors of PBDD/Fs, PBDEs, and Br-PAHs from different sources were 10.0, 5.21 × 10</span></span><sup>3</sup>, and 7.24 × 10<sup>3</sup> μg t<sup>−1</sup><span>, respectively. Therefore, the emission of brominated persistent organic pollutants (POPs) in the secondary copper industry should be of concern. The concentration of brominated POPs increased from the gas cooling stage to stack outlet due to the possible “memory effect” and the regenerated POPs were mainly low-brominated homologs. A comparison of brominated POPs with corresponding chlorinated analogs in the same process indicated that the formation pathway of Br-PAHs was consistent with that of chlorinated PAHs. However, unlike chlorinated dioxins and furans, PBDD/Fs can also be formed from PBDEs as precursors, leading to obvious increases in highly brominated furans. Therefore, inhibiting the unintentional formation of PBDEs is important for controlling brominated POPs emissions.</span></p></div>","PeriodicalId":361,"journal":{"name":"Journal of Hazardous Materials","volume":null,"pages":null},"PeriodicalIF":12.2000,"publicationDate":"2022-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Variation in the formation characteristics of PBDD/F, brominated PAH, and PBDE congeners along the secondary copper smelting processes\",\"authors\":\"Bingcheng Lin , Guorui Liu , Guanglong Wu , Changzhi Chen , Yong Liang , Pu Wang , Jianping Guo , Lili Yang , Rong Jin , Yuxiang Sun , Minghui Zheng\",\"doi\":\"10.1016/j.jhazmat.2022.129602\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Simultaneous determination of 58 congeners of polybrominated dibenzo-<em>p</em><span>-dioxins and dibenzofurans<span><span> (PBDD/Fs), brominated polycyclic aromatic hydrocarbons (Br-PAHs), and polybrominated diphenyl ethers (PBDEs) from multiple stages of industrial-scale secondary copper smelting plants was conducted with the aim of understanding their variations and control. In addition to the historical manufacture of PBDEs as brominated </span>flame retardants, this study confirmed that PBDEs can be unintentionally produced and released from the secondary copper industry. The average mass emission factors of PBDD/Fs, PBDEs, and Br-PAHs from different sources were 10.0, 5.21 × 10</span></span><sup>3</sup>, and 7.24 × 10<sup>3</sup> μg t<sup>−1</sup><span>, respectively. Therefore, the emission of brominated persistent organic pollutants (POPs) in the secondary copper industry should be of concern. The concentration of brominated POPs increased from the gas cooling stage to stack outlet due to the possible “memory effect” and the regenerated POPs were mainly low-brominated homologs. A comparison of brominated POPs with corresponding chlorinated analogs in the same process indicated that the formation pathway of Br-PAHs was consistent with that of chlorinated PAHs. However, unlike chlorinated dioxins and furans, PBDD/Fs can also be formed from PBDEs as precursors, leading to obvious increases in highly brominated furans. Therefore, inhibiting the unintentional formation of PBDEs is important for controlling brominated POPs emissions.</span></p></div>\",\"PeriodicalId\":361,\"journal\":{\"name\":\"Journal of Hazardous Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":12.2000,\"publicationDate\":\"2022-10-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Hazardous Materials\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0304389422013954\",\"RegionNum\":1,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Hazardous Materials","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0304389422013954","RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
Variation in the formation characteristics of PBDD/F, brominated PAH, and PBDE congeners along the secondary copper smelting processes
Simultaneous determination of 58 congeners of polybrominated dibenzo-p-dioxins and dibenzofurans (PBDD/Fs), brominated polycyclic aromatic hydrocarbons (Br-PAHs), and polybrominated diphenyl ethers (PBDEs) from multiple stages of industrial-scale secondary copper smelting plants was conducted with the aim of understanding their variations and control. In addition to the historical manufacture of PBDEs as brominated flame retardants, this study confirmed that PBDEs can be unintentionally produced and released from the secondary copper industry. The average mass emission factors of PBDD/Fs, PBDEs, and Br-PAHs from different sources were 10.0, 5.21 × 103, and 7.24 × 103 μg t−1, respectively. Therefore, the emission of brominated persistent organic pollutants (POPs) in the secondary copper industry should be of concern. The concentration of brominated POPs increased from the gas cooling stage to stack outlet due to the possible “memory effect” and the regenerated POPs were mainly low-brominated homologs. A comparison of brominated POPs with corresponding chlorinated analogs in the same process indicated that the formation pathway of Br-PAHs was consistent with that of chlorinated PAHs. However, unlike chlorinated dioxins and furans, PBDD/Fs can also be formed from PBDEs as precursors, leading to obvious increases in highly brominated furans. Therefore, inhibiting the unintentional formation of PBDEs is important for controlling brominated POPs emissions.
期刊介绍:
The Journal of Hazardous Materials serves as a global platform for promoting cutting-edge research in the field of Environmental Science and Engineering. Our publication features a wide range of articles, including full-length research papers, review articles, and perspectives, with the aim of enhancing our understanding of the dangers and risks associated with various materials concerning public health and the environment. It is important to note that the term "environmental contaminants" refers specifically to substances that pose hazardous effects through contamination, while excluding those that do not have such impacts on the environment or human health. Moreover, we emphasize the distinction between wastes and hazardous materials in order to provide further clarity on the scope of the journal. We have a keen interest in exploring specific compounds and microbial agents that have adverse effects on the environment.