Macduff Okuom, Mark Wilson, Jordan Groathouse, Junsik Lee, Dave Symonsbergen, Casey Gustafson, Mitch Trauernicht, Homar Barcena, Cassie Reicks, Sharmin Sikich, Raychelle Burks, Andrea Holmes
{"title":"提高光学亮度的荧光团的合成。","authors":"Macduff Okuom, Mark Wilson, Jordan Groathouse, Junsik Lee, Dave Symonsbergen, Casey Gustafson, Mitch Trauernicht, Homar Barcena, Cassie Reicks, Sharmin Sikich, Raychelle Burks, Andrea Holmes","doi":"10.4236/ijoc.2013.34037","DOIUrl":null,"url":null,"abstract":"<p><p>The synthesis and characterization of a novel fluorophore(<b>1</b>), with potential application as an optical brightener are reported. This compound was prepared by reacting 4,4-diaminostilbene-2,2-disulfonic acid with cyanuric chloride in the presence of Na<sub>2</sub>CO<sub>3</sub> followed by the addition of trityl aniline. Solution and solid state fluorescence demonstrated a strong blue/purple emission centered at 450 nm. <sup>1</sup>H-NMR spectroscopy, mass spectrometry analysis, elemental analysis, and DOSY-NMR were used for the characterization of the fluorophore.</p>","PeriodicalId":14243,"journal":{"name":"International Journal of Organic Chemistry","volume":"3 4","pages":"256-261"},"PeriodicalIF":0.0000,"publicationDate":"2013-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.4236/ijoc.2013.34037","citationCount":"2","resultStr":"{\"title\":\"Synthesis of a Fluorophore with Improved Optical Brightness.\",\"authors\":\"Macduff Okuom, Mark Wilson, Jordan Groathouse, Junsik Lee, Dave Symonsbergen, Casey Gustafson, Mitch Trauernicht, Homar Barcena, Cassie Reicks, Sharmin Sikich, Raychelle Burks, Andrea Holmes\",\"doi\":\"10.4236/ijoc.2013.34037\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The synthesis and characterization of a novel fluorophore(<b>1</b>), with potential application as an optical brightener are reported. This compound was prepared by reacting 4,4-diaminostilbene-2,2-disulfonic acid with cyanuric chloride in the presence of Na<sub>2</sub>CO<sub>3</sub> followed by the addition of trityl aniline. Solution and solid state fluorescence demonstrated a strong blue/purple emission centered at 450 nm. <sup>1</sup>H-NMR spectroscopy, mass spectrometry analysis, elemental analysis, and DOSY-NMR were used for the characterization of the fluorophore.</p>\",\"PeriodicalId\":14243,\"journal\":{\"name\":\"International Journal of Organic Chemistry\",\"volume\":\"3 4\",\"pages\":\"256-261\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2013-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.4236/ijoc.2013.34037\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Organic Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4236/ijoc.2013.34037\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Organic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4236/ijoc.2013.34037","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis of a Fluorophore with Improved Optical Brightness.
The synthesis and characterization of a novel fluorophore(1), with potential application as an optical brightener are reported. This compound was prepared by reacting 4,4-diaminostilbene-2,2-disulfonic acid with cyanuric chloride in the presence of Na2CO3 followed by the addition of trityl aniline. Solution and solid state fluorescence demonstrated a strong blue/purple emission centered at 450 nm. 1H-NMR spectroscopy, mass spectrometry analysis, elemental analysis, and DOSY-NMR were used for the characterization of the fluorophore.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
