An achieved strategy for magnetic biochar for removal of tetracyclines and fluoroquinolones: Adsorption and mechanism studies

In this study, poplar wood biochar modified with Fe₃O₄ (MPBC) was prepared using poplar wood as carbon source applied to remove tetracyclines and fluoroquinolones. The adsorption behavior was investigated by batch experiments, and a series of characterization techniques were used to study the corresponding mechanism. Characterizations indicated that pore filling, electrostatic interactions, π-π interaction, surface complexation, and hydrogen bond contributed to the adsorption of antibiotics on MPBC. Most importantly, the thermodynamic experiment results showed that the adsorption capacity of MPBC for tetracyclines (70.28–89.58 mg⋅g⁻¹) was significantly higher than fluoroquinolones (35.54–60.31 mg⋅g⁻¹), which was further explained by hydrogen bond interactions calculated from Conductor-like screening model for real solvents (COSMO-RS). In addition, the adsorption between MPBC and antibiotics was favorable at lower ionic strengths and neutral conditions. Conclusively, this study could provide a promising approach to controlling the pollution of tetracyclines and fluoroquinolones.