Yu Zhang, Zi-Wei Xia, Liang-jun Shen, Hao Tang, Xu-Feng Luo, Xing Li and Xunwen Xiao
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A 3D tetrathiafulvalene-based metal–organic framework with intramolecular charge transfer for efficient near-infrared photothermal conversion†
The selection of metal centers can endow donor–metal–accepter (D–M–A) type MOFs with progressive framework dimensions. 3D Cd-based MOFs with intramolecular charge transfer caused by D–M–A exhibit a satisfactory photothermal conversion efficiency of 35.7%, with the temperature rapidly rising from 25 °C to 201 °C in 7 s under 808 nm laser irradiation.
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