Govindasamy Palanisamy, Kandasamy Bhuvaneswari, Jintae Lee, A Viji, Mohd Shkir
{"title":"改进有毒污染物光催化分解的战略合理化：在MoS2纳米片上固定Bi2Te3纳米棒和V2O5纳米颗粒。","authors":"Govindasamy Palanisamy, Kandasamy Bhuvaneswari, Jintae Lee, A Viji, Mohd Shkir","doi":"10.1016/j.saa.2023.123400","DOIUrl":null,"url":null,"abstract":"<p><p>Researchers have become increasingly interested in solar energy based on semiconductor photocatalysts to remove hazardous pollutants and clean the environment. In this work, an efficient MoS<sub>2</sub>-Bi<sub>2</sub>Te<sub>3</sub>-V<sub>2</sub>O<sub>5</sub> nanocomposite has been prepared through wet impregnation method. MoS<sub>2</sub>-Bi<sub>2</sub>Te<sub>3</sub>-V<sub>2</sub>O<sub>5</sub> photocatalyst was utilized to decompose the MB and Rh B dyes. The photocatalytic efficiency (Rh B) of MoS<sub>2</sub>-Bi<sub>2</sub>Te<sub>3</sub>-V<sub>2</sub>O<sub>5</sub> nanocomposite (95.19 %) was higher than 2.70 times of Bi<sub>2</sub>Te<sub>3</sub> nanorods, 1.55 times of V<sub>2</sub>O<sub>5</sub> nanoparticles, 1.68 times of MoS<sub>2</sub> nanosheets, 1.50 times of MoS<sub>2</sub>-Bi<sub>2</sub>Te<sub>3,</sub> and 1.21 times of MoS<sub>2</sub>-V<sub>2</sub>O<sub>5</sub> nanocomposite, respectively. Recycling tests conducted on the MoS<sub>2</sub>-Bi<sub>2</sub>Te<sub>3</sub>-V<sub>2</sub>O<sub>5</sub> nanocomposite revealed its high stability and durability. The outcomes obtained from the scavenger test suggest that the photogenerated hydroxyl radicals play a chief role in the photocatalytic performance of Rh B dye in the MoS<sub>2</sub>-Bi<sub>2</sub>Te<sub>3</sub>-V<sub>2</sub>O<sub>5</sub> nanocomposite, respectively. The enhanced photocatalytic performance of the MoS<sub>2</sub>-Bi<sub>2</sub>Te<sub>3</sub>-V<sub>2</sub>O<sub>5</sub> nanocomposite is ascribed to the strong hybrid formation of Bi<sub>2</sub>Te<sub>3</sub>, V<sub>2</sub>O<sub>5</sub>, and MoS<sub>2</sub> nanosheets, respectively. Consequently, the straightforward and readily synthesized MoS<sub>2</sub>-Bi<sub>2</sub>Te<sub>3</sub>-V<sub>2</sub>O<sub>5</sub> nanocomposite can serve as an economical, highly effective material for environmental applications.</p>","PeriodicalId":94213,"journal":{"name":"Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy","volume":"304 ","pages":"123400"},"PeriodicalIF":0.0000,"publicationDate":"2024-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Strategic rationalization for improved photocatalytic decomposition of toxic pollutants: Immobilizing Bi<sub>2</sub>Te<sub>3</sub> nanorods and V<sub>2</sub>O<sub>5</sub> nanoparticles over MoS<sub>2</sub> nanosheets.\",\"authors\":\"Govindasamy Palanisamy, Kandasamy Bhuvaneswari, Jintae Lee, A Viji, Mohd Shkir\",\"doi\":\"10.1016/j.saa.2023.123400\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Researchers have become increasingly interested in solar energy based on semiconductor photocatalysts to remove hazardous pollutants and clean the environment. In this work, an efficient MoS<sub>2</sub>-Bi<sub>2</sub>Te<sub>3</sub>-V<sub>2</sub>O<sub>5</sub> nanocomposite has been prepared through wet impregnation method. MoS<sub>2</sub>-Bi<sub>2</sub>Te<sub>3</sub>-V<sub>2</sub>O<sub>5</sub> photocatalyst was utilized to decompose the MB and Rh B dyes. The photocatalytic efficiency (Rh B) of MoS<sub>2</sub>-Bi<sub>2</sub>Te<sub>3</sub>-V<sub>2</sub>O<sub>5</sub> nanocomposite (95.19 %) was higher than 2.70 times of Bi<sub>2</sub>Te<sub>3</sub> nanorods, 1.55 times of V<sub>2</sub>O<sub>5</sub> nanoparticles, 1.68 times of MoS<sub>2</sub> nanosheets, 1.50 times of MoS<sub>2</sub>-Bi<sub>2</sub>Te<sub>3,</sub> and 1.21 times of MoS<sub>2</sub>-V<sub>2</sub>O<sub>5</sub> nanocomposite, respectively. Recycling tests conducted on the MoS<sub>2</sub>-Bi<sub>2</sub>Te<sub>3</sub>-V<sub>2</sub>O<sub>5</sub> nanocomposite revealed its high stability and durability. The outcomes obtained from the scavenger test suggest that the photogenerated hydroxyl radicals play a chief role in the photocatalytic performance of Rh B dye in the MoS<sub>2</sub>-Bi<sub>2</sub>Te<sub>3</sub>-V<sub>2</sub>O<sub>5</sub> nanocomposite, respectively. The enhanced photocatalytic performance of the MoS<sub>2</sub>-Bi<sub>2</sub>Te<sub>3</sub>-V<sub>2</sub>O<sub>5</sub> nanocomposite is ascribed to the strong hybrid formation of Bi<sub>2</sub>Te<sub>3</sub>, V<sub>2</sub>O<sub>5</sub>, and MoS<sub>2</sub> nanosheets, respectively. Consequently, the straightforward and readily synthesized MoS<sub>2</sub>-Bi<sub>2</sub>Te<sub>3</sub>-V<sub>2</sub>O<sub>5</sub> nanocomposite can serve as an economical, highly effective material for environmental applications.</p>\",\"PeriodicalId\":94213,\"journal\":{\"name\":\"Spectrochimica acta. 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Part A, Molecular and biomolecular spectroscopy","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1016/j.saa.2023.123400","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2023/9/12 0:00:00","PubModel":"Epub","JCR":"","JCRName":"","Score":null,"Total":0}
Strategic rationalization for improved photocatalytic decomposition of toxic pollutants: Immobilizing Bi2Te3 nanorods and V2O5 nanoparticles over MoS2 nanosheets.
Researchers have become increasingly interested in solar energy based on semiconductor photocatalysts to remove hazardous pollutants and clean the environment. In this work, an efficient MoS2-Bi2Te3-V2O5 nanocomposite has been prepared through wet impregnation method. MoS2-Bi2Te3-V2O5 photocatalyst was utilized to decompose the MB and Rh B dyes. The photocatalytic efficiency (Rh B) of MoS2-Bi2Te3-V2O5 nanocomposite (95.19 %) was higher than 2.70 times of Bi2Te3 nanorods, 1.55 times of V2O5 nanoparticles, 1.68 times of MoS2 nanosheets, 1.50 times of MoS2-Bi2Te3, and 1.21 times of MoS2-V2O5 nanocomposite, respectively. Recycling tests conducted on the MoS2-Bi2Te3-V2O5 nanocomposite revealed its high stability and durability. The outcomes obtained from the scavenger test suggest that the photogenerated hydroxyl radicals play a chief role in the photocatalytic performance of Rh B dye in the MoS2-Bi2Te3-V2O5 nanocomposite, respectively. The enhanced photocatalytic performance of the MoS2-Bi2Te3-V2O5 nanocomposite is ascribed to the strong hybrid formation of Bi2Te3, V2O5, and MoS2 nanosheets, respectively. Consequently, the straightforward and readily synthesized MoS2-Bi2Te3-V2O5 nanocomposite can serve as an economical, highly effective material for environmental applications.
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