AA70增强玉米壳颗粒在NaCl/H2SO4浓度下的腐蚀行为

O. Falodun, R. Loto
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引用次数: 0

摘要

采用电化学技术和光学显微镜研究了玉米壳颗粒和热处理对AA70基体复合材料在1.5wt.%NaCl/0.0125MH2SO4浓度下腐蚀行为的影响。结果表明,热处理后样品具有相似的阳极-阴极极化行为,没有钝化。然而,在1.5wt.%NaCl/0.0125M H2SO4浓度下,热处理的AA70基体复合材料比未处理的AA70%基体复合材料更耐腐蚀。具有15wt.%玉米壳和粒径为300μm的增强AA70基体的复合材料显示出最小的腐蚀倾向,并且在氯离子和硫酸根离子条件下热力学最稳定。因此,与AA70材料相比,热处理的AA70基体复合材料在1.5wt.%NaCl/0.0125M H2SO4溶液中的腐蚀行为更好。此外,高浓度侵蚀性氯离子的存在增加了腐蚀敏感性,玉米壳颗粒破坏了稳定的氧化膜,导致氯离子吸附增加。光学显微镜检查表明材料表面存在局部腐蚀。
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Corrosion Behavior of AA70 Reinforced Zea mays Husk Particle in NaCl/H2SO4 Concentrations
The effects of Zea mays husk particle and heat treatment on the corrosion behavior of AA70 matrix composite in 1.5 wt.% NaCl/0.0125 M H2SO4 concentrations were studied using an electrochemical technique and optical microscopy. Results showed that the samples had similar anodic-cathodic polarization behavior after heat treatment, with no passivation. However, the heat-treated AA70 matrix composites were more corrosion-resistant than the untreated AA70 matrix composite material in 1.5 wt.% NaCl/0.0125 M H2SO4 concentrations. The composite with 15 wt.% Zea mays husk and a particle size of 300 μm reinforced AA70 matrix revealed the least corrosive tendency and is the most thermodynamically stable in chloride and sulphate ions conditions. Therefore, the corrosion behavior of heat-treated AA70 matrix composites was better compared to that of AA70 material in 1.5 wt.% NaCl/0.0125 M H2SO4 solution. Furthermore, the presence of a high concentration of aggressive chloride ions increases the corrosion susceptibility, and the Zea mays husk particle breaks down the stable oxide film, resulting in increased chloride ion adsorption. The optical microscopy examination suggested the presence of localized corrosion on the material surface.
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来源期刊
Applied Science and Engineering Progress
Applied Science and Engineering Progress Engineering-Engineering (all)
CiteScore
4.70
自引率
0.00%
发文量
56
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