论酸碱统一理论:张哈素、埃里克·r·塞里、现代理论化学和化学哲学

IF 1.8 3区 化学 Q1 HISTORY & PHILOSOPHY OF SCIENCE Foundations of Chemistry Pub Date : 2023-03-03 DOI:10.1007/s10698-022-09456-5
Dean J. Tantillo, Jeffrey I. Seeman
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引用次数: 3

摘要

最近几位主要的化学哲学家的出版物集中在定义、范围、效用和处理酸碱度问题的命名法上。在本文中,分子轨道理论被用来解释所有的酸碱反应,结论是一种底物“碱”的最高占据分子轨道(HOMO)与另一种底物“酸”的最低未占据分子轨道(LUMO)的相互作用决定了这种体系的反应性。这个范例提供了对所有酸碱反应的理解,以及其他表面上看起来不像酸碱反应的反应,但它们具有那种化学的基本基础。与其像化学哲学文献中建议的那样无法确定对酸度和碱度的统一理解,我们建议酸度和碱度安全地适合许多其他反应的分类,使用经典化学知识,前量子化学,是不可能的。我们强烈支持在哲学科学思想的发展中运用一切科学知识和经验。我们进一步建议增加科学哲学家和科学家之间的互动,以便所有学者都能从其他学科的价值观、知识和观点中受益。
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On a unified theory of acids and bases: Hasok Chang, Eric R. Scerri, modern theoretical chemistry, and the philosophy of chemistry

Recent publications by several leading philosophers of chemistry have focused on the definition, scope, utility, and nomenclature of issues dealing with acidity and basicity. In this paper, molecular orbital theory is used to explain all acid–base reactions, concluding that the interaction of the highest occupied molecular orbital (HOMO) of one substrate, “the base,” with the lowest unoccupied molecular orbital (LUMO) of a second substrate, “the acid,” determines the reactivity of such systems. This paradigm provides an understanding of all acid–base reactions as well as other reactions which, on the surface, may not seem like acid–base reactions but which have fundamental underpinnings of that kind of chemistry. Rather than being unable to determine a unified understanding of acidity and basicity as suggested in the philosophy of chemistry literature, we propose that acidity and basicity fit securely in a classification of many other reactions that, using classical chemistry knowledge, pre-quantum chemistry, would not be possible. We strongly support the use of all scientific knowledge and experience in the development of the ideas in the philosophy science. We further suggest increased interactions between philosophers of science and scientists, so that all scholars benefit from the values, knowledge, and perspectives of other disciplines.

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来源期刊
Foundations of Chemistry
Foundations of Chemistry HISTORY & PHILOSOPHY OF SCIENCE-
自引率
22.20%
发文量
35
期刊介绍: Foundations of Chemistry is an international journal which seeks to provide an interdisciplinary forum where chemists, biochemists, philosophers, historians, educators and sociologists with an interest in foundational issues can discuss conceptual and fundamental issues which relate to the `central science'' of chemistry. Such issues include the autonomous role of chemistry between physics and biology and the question of the reduction of chemistry to quantum mechanics. The journal will publish peer-reviewed academic articles on a wide range of subdisciplines, among others: chemical models, chemical language, metaphors, and theoretical terms; chemical evolution and artificial self-replication; industrial application, environmental concern, and the social and ethical aspects of chemistry''s professionalism; the nature of modeling and the role of instrumentation in chemistry; institutional studies and the nature of explanation in the chemical sciences; theoretical chemistry, molecular structure and chaos; the issue of realism; molecular biology, bio-inorganic chemistry; historical studies on ancient chemistry, medieval chemistry and alchemy; philosophical and historical articles; and material of a didactic nature relating to all topics in the chemical sciences. Foundations of Chemistry plans to feature special issues devoted to particular themes, and will contain book reviews and discussion notes. Audience: chemists, biochemists, philosophers, historians, chemical educators, sociologists, and other scientists with an interest in the foundational issues of science.
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