{"title":"铜-EDTA氨-硫代硫酸金溶解体系的电化学分析","authors":"P. Xiang, G. Ye","doi":"10.1515/gps-2023-0110","DOIUrl":null,"url":null,"abstract":"Abstract Ethylenediaminetetraacetic acid disodium (EDTA) can form stable complexes with many metals. To improve the leaching rate of gold and the consumption rate of thiosulfate, EDTA and ammonia were combined with copper ions to form a copper-EDTA-ammonia-thiosulfate system. Electrochemical methods were used to study the effect of thiosulfate, copper ion, EDTA, and polarization voltage. The results showed that increasing the concentrations of thiosulfate, copper ions, and EDTA promoted the dissolution of gold, which changed from electrochemical control to diffusion control after adding EDTA. The order of influence was thiosulfate > EDTA > copper ion. The pure gold leaching experiment showed that the dissolution rate of gold in the EDTA-ammonium-copper thiosulfate system was higher than that in the EDTA-copper-thiosulfuric acid system, thus achieving synergistic gold leaching.","PeriodicalId":12758,"journal":{"name":"Green Processing and Synthesis","volume":"12 1","pages":""},"PeriodicalIF":3.8000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electrochemical analysis of copper-EDTA-ammonia-gold thiosulfate dissolution system\",\"authors\":\"P. Xiang, G. Ye\",\"doi\":\"10.1515/gps-2023-0110\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract Ethylenediaminetetraacetic acid disodium (EDTA) can form stable complexes with many metals. To improve the leaching rate of gold and the consumption rate of thiosulfate, EDTA and ammonia were combined with copper ions to form a copper-EDTA-ammonia-thiosulfate system. Electrochemical methods were used to study the effect of thiosulfate, copper ion, EDTA, and polarization voltage. The results showed that increasing the concentrations of thiosulfate, copper ions, and EDTA promoted the dissolution of gold, which changed from electrochemical control to diffusion control after adding EDTA. The order of influence was thiosulfate > EDTA > copper ion. The pure gold leaching experiment showed that the dissolution rate of gold in the EDTA-ammonium-copper thiosulfate system was higher than that in the EDTA-copper-thiosulfuric acid system, thus achieving synergistic gold leaching.\",\"PeriodicalId\":12758,\"journal\":{\"name\":\"Green Processing and Synthesis\",\"volume\":\"12 1\",\"pages\":\"\"},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2023-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Green Processing and Synthesis\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1515/gps-2023-0110\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Green Processing and Synthesis","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1515/gps-2023-0110","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Electrochemical analysis of copper-EDTA-ammonia-gold thiosulfate dissolution system
Abstract Ethylenediaminetetraacetic acid disodium (EDTA) can form stable complexes with many metals. To improve the leaching rate of gold and the consumption rate of thiosulfate, EDTA and ammonia were combined with copper ions to form a copper-EDTA-ammonia-thiosulfate system. Electrochemical methods were used to study the effect of thiosulfate, copper ion, EDTA, and polarization voltage. The results showed that increasing the concentrations of thiosulfate, copper ions, and EDTA promoted the dissolution of gold, which changed from electrochemical control to diffusion control after adding EDTA. The order of influence was thiosulfate > EDTA > copper ion. The pure gold leaching experiment showed that the dissolution rate of gold in the EDTA-ammonium-copper thiosulfate system was higher than that in the EDTA-copper-thiosulfuric acid system, thus achieving synergistic gold leaching.
期刊介绍：
Green Processing and Synthesis is a bimonthly, peer-reviewed journal that provides up-to-date research both on fundamental as well as applied aspects of innovative green process development and chemical synthesis, giving an appropriate share to industrial views. The contributions are cutting edge, high-impact, authoritative, and provide both pros and cons of potential technologies. Green Processing and Synthesis provides a platform for scientists and engineers, especially chemists and chemical engineers, but is also open for interdisciplinary research from other areas such as physics, materials science, or catalysis.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
