一种氮肥生产工艺的优化

IF 0.2 Q4 CHEMISTRY, MULTIDISCIPLINARY Periodico Tche Quimica Pub Date : 2020-12-20 DOI:10.52571/ptq.v17.n36.2020.202_periodico36_pgs_186_195.pdf
A. D. Kydyraliyeva, U. Besterekov, U. Nazarbek, A. Bolysbek, K. N. Urakov
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引用次数: 0

摘要

硝酸铵是全球最常见和最有用的氮肥,由于其火灾和爆炸危险,其需求量大幅下降。对于农业来说,复合肥料是最可取的。因此,优化技术的开发是一项紧迫的任务。本研究旨在开发基于当前硝酸铵生产的蒸发第一阶段和磨细磷矿的溶液混合物的NP肥料技术,以获得具有改善的消费者和农业化学性能的目标产品。确定了硝酸铵和磷矿石比耗的最佳工艺操作参数。结果表明,营养元素N/P2O5在肥料配方中的比例调节为23/5%;21/6%;19/7%;13/10%和11/11%。采用可旋转规划的Box-Hunter二阶建模方法对数据进行了实现。确定了自变量对目标产品中营养成分含量的影响——硝酸铵和磨石的比消耗量。已经确定,它们的变化伴随着两个相反的过程,即硝酸铵的比消耗量增加,同时磷矿石的比消耗减少,反之亦然;并且它随着硝酸铵的比消耗的降低而降低,同时初始混合物中磨碎的磷矿石的比消耗增加。对于自变量对产品中营养成分比例的影响,找到了一个适当的回归方程。结果表明,随着初始混合物从0.36t到0.67t以及产品从0.54t到0.29t的相应变化,N/P2O5比从2.51增加到4.68。此外,可以获得一整套具有改进的农用化学和消费特性的NP肥料,其成分中NP的总含量为25%至28%。硝酸铵、磷矿石、营养物质、氮、五氧化二磷
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OPTIMIZATION OF AN NP-FERTILIZER PRODUCTION TECHNOLOGY
Ammonium nitrate is the most common and useful nitrogen fertilizer globally, and its demand has decreased significantly due to its fire and explosion hazard. For the agricultural industry, compound fertilizers are most preferable. So, optimized technology’s development is an urgent task. This study aimed to develop NP-fertilizers technology based on the solution mixture of the evaporation’s first stage of the current production of ammonium nitrate and ground phosphate rock to obtain the target product with improved consumer and agrochemical properties. It was established optimal operating parameters of the technology for specific consumption of ammonium nitrate and ground phosphate rock. The results showed the ratio regulation of nutrient elements N/P2O5 in fertilizer formulations as 23/5%; 21/6%; 19/7%; 13/10%, and 11/11%. The method of rotatable planning-Box-Hunter second-order modeling was used to achieve the data. The independent variables’ influence – specific consumption of ammonium nitrate and ground phosphate rock on the nutrients’ content in the target products were determined. It has been established that two opposite processes accompany their change, that is, it increases by an increase in the specific consumption of ammonium nitrate with a simultaneous decrease in the specific consumption of ground phosphate rock, and vice versa; and it decreases with a decrease in the specific consumption of ammonium nitrate with a simultaneous increase in the particular consumption of ground phosphate rock in the initial mixture. An adequate regression equation was found for the independent variables’ influence on the nutrients’ ratios in products. It was shown that, with corresponding changes in the initial mixture from 0.36 t to 0.67t and 0.54t to 0.29t in the products, the N/ P2O5 ratios increased from 2.51 to 4.68. Moreover, it is possible to obtain a whole set of NP-fertilizers with improved agrochemical and consumer properties, with a total NP content of 25% to 28% in their composition. monium nitrate, ground phosphate rock, nutrients, nitrogen, phosphorus pentoxide
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Periodico Tche Quimica
Periodico Tche Quimica CHEMISTRY, MULTIDISCIPLINARY-
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期刊介绍: The Journal publishes original research papers, review articles, short communications (scientific publications), book reviews, forum articles, announcements or letters as well as interviews. Researchers from all countries are invited to publish on its pages.
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