质子交换膜燃料电池中铂本体改性全氟膜的物理化学性质和性能特征

IF 2 Q4 CHEMISTRY, PHYSICAL Membranes and Membrane Technologies Pub Date : 2023-04-04 DOI:10.1134/S2517751623010043
D. S. Kudashova, I. V. Falina, N. A. Kononenko, K. S. Demidenko
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引用次数: 1

摘要

介绍了铂本体改性全氟膜在质子交换膜燃料电池(PEMFC)中的应用结果。讨论了铂改性后膜的物理化学和输运特性的变化以及膜在PEMFC中不同运行阶段的变化。研究了标准接触孔隙法测得的厚度、半径孔分布、电导率的浓度依赖性和电流-电压特性。研究了双金属电催化剂中铜对全氟膜性能的影响。由于形成了自湿结构,使用商业和双金属催化剂和铂本体改性膜的PEMFC效率都有所提高。
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Physicochemical Properties and Performance Characteristics of Perfluorinated Membranes Bulk Modified with Platinum during Operation in Proton Exchange Membrane Fuel Cell

The results of application of platinum bulk modified perfluorinated membranes in proton exchange membrane fuel cell (PEMFC) are presented. The change in physicochemical and transport characteristics of the membranes after modification with platinum and at different stages of their operation in the PEMFC are also discussed. The thickness, radius pore distribution obtained by the standard contact porosimetry method, the concentration dependences of the conductivity, and the current-voltage characteristic are studied. The influence of copper in bimetallic electrocatalyst on the characteristics of the perfluorinated membrane are considered. An increase in the efficiency of PEMFC with both commercial and bimetallic catalysts and platinum bulk modified membranes due to the formation of a self-humidifying structure is found.

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来源期刊
CiteScore
3.10
自引率
31.20%
发文量
38
期刊介绍: The journal Membranes and Membrane Technologies publishes original research articles and reviews devoted to scientific research and technological advancements in the field of membranes and membrane technologies, including the following main topics:novel membrane materials and creation of highly efficient polymeric and inorganic membranes;hybrid membranes, nanocomposites, and nanostructured membranes;aqueous and nonaqueous filtration processes (micro-, ultra-, and nanofiltration; reverse osmosis);gas separation;electromembrane processes and fuel cells;membrane pervaporation and membrane distillation;membrane catalysis and membrane reactors;water desalination and wastewater treatment;hybrid membrane processes;membrane sensors;membrane extraction and membrane emulsification;mathematical simulation of porous structures and membrane separation processes;membrane characterization;membrane technologies in industry (energy, mineral extraction, pharmaceutics and medicine, chemistry and petroleum chemistry, food industry, and others);membranes and protection of environment (“green chemistry”).The journal has been published in Russian already for several years, English translations of the content used to be integrated in the journal Petroleum Chemistry. This journal is a split off with additional topics.
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