植物基填料复合材料的合成与性能研究

IF 2.8 Q2 ENGINEERING, CHEMICAL ChemEngineering Pub Date : 2023-04-18 DOI:10.3390/chemengineering7020038
N. Cherkashina, Z. Pavlenko, D. S. Matveenko, S. Domarev, Dar’ya Vasil’yevna Pushkarskaya, Dar’ya Aleksandrovna Ryzhikh
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引用次数: 1

摘要

本文介绍了以环氧树脂粘结剂和植物填料为基础合成聚合物复合材料的结果。预干燥和粉状的小麦秸秆被用作植物填料。麦秆在复合材料中的含量在10至50wt%之间。研究了麦秆含量对复合材料的热性能、机械性能和表面性能的影响。此外,还对样品的耐腐蚀性进行了研究。评估了复合材料的疏水-亲水表面平衡,并研究了其自由表面能。少量(高达30wt.%)小麦秸秆的引入使聚合物的抗弯强度从18.65±1.12MPa提高到22.61±0.91MPa;当含量大于40wt%时,观察到强度降低。即使麦秆粉末含量为50 wt.%,弯曲强度也为11.52±1.03 MPa,这与建筑材料的强度相对应。环氧粘合剂的工作温度上限为306°C,麦秆含量为30 wt.-264°C的复合材料的工作温度下限为306°C。纯聚合物的表面表现出亲水性。纯环氧树脂样品的水润湿接触角平均值为84.96±9.03°。引入30wt.%的麦草粉填料使表面变成疏水性表面(水润湿接触角度平均值为96.69±5.71°)。所开发的复合材料可用于家具生产,包括桌面或地板面板。未来的研究将集中在扩大聚合物复合材料的植物基填料的类型上。
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Synthesis and Characteristics of Composite Material with a Plant-Based Filler
The article presents the results of synthesis of polymeric composite material based on epoxy binder and plant-based filler. Pre-dried and powdered wheat straw was used as a plant-based filler. The wheat straw content in the composite varied from 10 to 50 wt.%. Thermal, mechanical, and surface properties of composites depending on the wheat straw content were researched. In addition, the samples were studied for resistance to corrosive environments. The hydrophobic–hydrophilic surface balance of composites was evaluated, and their free surface energy was studied. Introduction of wheat straw in small amounts (up to 30 wt.%) increases bending strength of polymer from 18.65 ± 1.12 MPa to 22.61 ± 0.91 MPa; when the content is more than 40 wt.%, reduction of strength is observed. Even with a wheat straw powder content of 50 wt.%, the bending strength is 11.52 ± 1.03 MPa, which corresponds to the strength of the construction material. The upper limit of working temperature for the epoxy binder is 306 °C, and for the composite with the wheat straw content of 30 wt.%—264 °C. The surface of the pure polymer shows a hydrophilic character. The average value of the water wetting contact angle of the pure epoxy sample is 84.96 ± 9.03°. The introduction of 30 wt.% of wheat straw powder filler transforms the surface into hydrophobic one (average value of water wetting contact angle is 96.69 ± 5.71°). The developed composites can be applied in furniture production including tabletops or panels for floors. Future research will focus on expanding the types of plant-based fillers for polymer composites.
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来源期刊
ChemEngineering
ChemEngineering Engineering-Engineering (all)
CiteScore
4.00
自引率
4.00%
发文量
88
审稿时长
11 weeks
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