利用电导率估算压实膨润土的膨胀应变和膨胀压力

IF 5.3 2区 地球科学 Q2 CHEMISTRY, PHYSICAL Applied Clay Science Pub Date : 2023-09-15 DOI:10.1016/j.clay.2023.107040
Jongmuk Won , Jang-Un Kim , Hyunwook Choo
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引用次数: 2

摘要

膨胀应变或膨胀压力的估算对于预测膨润土屏障的压实特性是非常重要的。在本研究中,在自由膨胀和受限条件下测量了压实膨润土的电导率,以研究测量电导率对膨胀应变或膨胀压力的可预测性。水渗透对膨润土电导率的影响与溶胀应变或溶胀压力的影响在定性上是一致的,这意味着电导率的监测可以用来检测膨润土溶胀过程的开始和结束或压实后膨润土的任何内部变化。基于钙基膨润土与NaCl溶液的水化实验结果,建立了归一化膨胀应变与归一化电导率、归一化膨胀压力与归一化电导率的关系,并通过钙基膨润土与KCl、CaCl2溶液和钠基膨润土与NaCl溶液的水化实验结果进行了验证。最后,讨论了电导率在估算溶胀参数和监测溶胀过程中的局限性和可能性。
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Estimation of the swelling strain and swelling pressure of compacted bentonite using electrical conductivity

Estimation of the swelling strain or swelling pressure is important for predicting the behavior of compacted bentonite barriers. In this study, the electrical conductivity of compacted bentonite was measured under free-swell and confined conditions to investigate the predictability of swelling strain or swelling pressure from the measured electrical conductivity. The evolution of electrical conductivity by water penetration was qualitatively consistent with that of swelling strain or swelling pressure, implying that monitoring electrical conductivity could be used to detect the initiation and termination of swelling process or any internal changes in compacted bentonite. The relationships between normalized swelling strain and normalized electrical conductivity, and between normalized swelling pressure and normalized electrical conductivity were developed based on the results of Ca-bentonite hydrated with NaCl solution, and those were verified using the results of Ca-bentonite hydrated with KCl and CaCl2 solutions, and Na-bentonite hydrated with NaCl solution. Finally, the limitations and possibilities of using electrical conductivity in estimating swelling parameters and monitoring swelling process were discussed in this study.

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来源期刊
Applied Clay Science
Applied Clay Science 地学-矿物学
CiteScore
10.30
自引率
10.70%
发文量
289
审稿时长
39 days
期刊介绍: Applied Clay Science aims to be an international journal attracting high quality scientific papers on clays and clay minerals, including research papers, reviews, and technical notes. The journal covers typical subjects of Fundamental and Applied Clay Science such as: • Synthesis and purification • Structural, crystallographic and mineralogical properties of clays and clay minerals • Thermal properties of clays and clay minerals • Physico-chemical properties including i) surface and interface properties; ii) thermodynamic properties; iii) mechanical properties • Interaction with water, with polar and apolar molecules • Colloidal properties and rheology • Adsorption, Intercalation, Ionic exchange • Genesis and deposits of clay minerals • Geology and geochemistry of clays • Modification of clays and clay minerals properties by thermal and physical treatments • Modification by chemical treatments with organic and inorganic molecules(organoclays, pillared clays) • Modification by biological microorganisms. etc...
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