Daniel Moro Druzian, Pâmela Cristine Ladwig Muraro, Leandro Rodrigues Oviedo, Matheus Londero da Costa, Robson Dias Wouters, Sthéfany Nunes Loureiro, William Leonardo da Silva, João Henrique Zimnoch dos Santos
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The results confirmed the production of a nanoadsorbent with an average particle diameter around 25?nm. (TiO<sub>2</sub>@MnO<sub>2</sub>)-NPs showed negative surface charge (??11.32?mV), and pH<sub>ZCP</sub>?≈?7.65. Regarding Hg<sup>2+</sup> adsorption, the removal was 86.15%. Adsorption data were fitted by Khan (<i>R</i><sup>2</sup> 0.96, <i>q</i><sub>e</sub>?=?28.07?mg?g<sup>?1</sup>) and intraparticle diffusion (<i>R</i><sup>2</sup> 0.97, <i>q</i><sub><i>t</i></sub>?=?28.84?mg?g<sup>?1</sup>) models. Thermodynamics suggested the adsorption is exothermic process (Δ<i>H</i>?=???73.93?kJ?mol<sup>?1</sup>), with decrease of the randomness (Δ<i>S</i>?=?0.24?kJ?mol<sup>?1</sup>?K<sup>?1</sup>) in the solid–liquid interface, being favorable under temperature below 298.15?K (Δ<i>G</i>?=???1.16?kJ?mol<sup>?1</sup>). (TiO<sub>2</sub>@MnO<sub>2</sub>)-NPs resulted in more than 80% Hg<sup>2+</sup> removal after six cycles of adsorption. Therefore, nanoparticles containing titanium and manganese can be effectively used for the adsorption of Hg<sup>2+</sup> ions, collaborating with the environment.</p></div>","PeriodicalId":643,"journal":{"name":"Journal of Material Cycles and Waste Management","volume":"25 5","pages":"2691 - 2705"},"PeriodicalIF":2.7000,"publicationDate":"2023-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Removal of Hg2+ ions by adsorption using (TiO2@MnO2)-NPs nanocomposite\",\"authors\":\"Daniel Moro Druzian, Pâmela Cristine Ladwig Muraro, Leandro Rodrigues Oviedo, Matheus Londero da Costa, Robson Dias Wouters, Sthéfany Nunes Loureiro, William Leonardo da Silva, João Henrique Zimnoch dos Santos\",\"doi\":\"10.1007/s10163-023-01743-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Waste water contaminated with inorganic mercury is considered a serious environmental problem, mainly due to the hazardous effects this contaminant causes on human health. 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Thermodynamics suggested the adsorption is exothermic process (Δ<i>H</i>?=???73.93?kJ?mol<sup>?1</sup>), with decrease of the randomness (Δ<i>S</i>?=?0.24?kJ?mol<sup>?1</sup>?K<sup>?1</sup>) in the solid–liquid interface, being favorable under temperature below 298.15?K (Δ<i>G</i>?=???1.16?kJ?mol<sup>?1</sup>). (TiO<sub>2</sub>@MnO<sub>2</sub>)-NPs resulted in more than 80% Hg<sup>2+</sup> removal after six cycles of adsorption. Therefore, nanoparticles containing titanium and manganese can be effectively used for the adsorption of Hg<sup>2+</sup> ions, collaborating with the environment.</p></div>\",\"PeriodicalId\":643,\"journal\":{\"name\":\"Journal of Material Cycles and Waste Management\",\"volume\":\"25 5\",\"pages\":\"2691 - 2705\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2023-07-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Material Cycles and Waste Management\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10163-023-01743-3\",\"RegionNum\":4,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENVIRONMENTAL SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Material Cycles and Waste Management","FirstCategoryId":"93","ListUrlMain":"https://link.springer.com/article/10.1007/s10163-023-01743-3","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 1
摘要
被无机汞污染的废水被认为是一个严重的环境问题，主要是因为这种污染物对人类健康造成有害影响。因此，本研究旨在评价生物合成获得的双金属纳米吸附剂(TiO2@MnO2)-NPs)在吸附去除汞离子(Hg2+)中的潜力。(TiO2@MnO2)-NPs是由芦荟和苦参提取物合成的。采用XRD、ZP和pHZCP对纳米吸附剂进行了表征。结果表明，制备的纳米吸附剂的平均粒径约为25nm。(TiO2@MnO2)-NPs表面电荷为负(11.32 mV)， pHZCP≈7.65。对Hg2+的吸附率为86.15%。吸附数据采用Khan模型(R2 0.96, qe = 28.07 mg g 1)和颗粒内扩散模型(R2 0.97, qt = 28.84 mg g 1)拟合。热力学结果表明，吸附过程为放热过程(ΔH?= 73.93?kJ?mol?1)，吸附过程的随机性降低(ΔS?= 0.24?kJ?mol?1?K?1)，温度低于298.15?K(ΔG ? = ? ? 1.16 kJ ?摩尔? 1)。(TiO2@MnO2)-NPs经过6次循环吸附后，Hg2+去除率超过80%。因此，含有钛和锰的纳米颗粒可以有效地用于吸附Hg2+离子，与环境协同作用。
Removal of Hg2+ ions by adsorption using (TiO2@MnO2)-NPs nanocomposite
Waste water contaminated with inorganic mercury is considered a serious environmental problem, mainly due to the hazardous effects this contaminant causes on human health. Thus, the present work aims to evaluate the potentiality of the bimetallic nanoadsorbent ((TiO2@MnO2)-NPs) obtained from the biosynthesis in the mercury ions (Hg2+) removal by adsorption. (TiO2@MnO2)-NPs was synthesized from Aloe vera and Matricaria recutita extracts. The nanoadsorbent was characterized by XRD, ZP, and pHZCP. The results confirmed the production of a nanoadsorbent with an average particle diameter around 25?nm. (TiO2@MnO2)-NPs showed negative surface charge (??11.32?mV), and pHZCP?≈?7.65. Regarding Hg2+ adsorption, the removal was 86.15%. Adsorption data were fitted by Khan (R2 0.96, qe?=?28.07?mg?g?1) and intraparticle diffusion (R2 0.97, qt?=?28.84?mg?g?1) models. Thermodynamics suggested the adsorption is exothermic process (ΔH?=???73.93?kJ?mol?1), with decrease of the randomness (ΔS?=?0.24?kJ?mol?1?K?1) in the solid–liquid interface, being favorable under temperature below 298.15?K (ΔG?=???1.16?kJ?mol?1). (TiO2@MnO2)-NPs resulted in more than 80% Hg2+ removal after six cycles of adsorption. Therefore, nanoparticles containing titanium and manganese can be effectively used for the adsorption of Hg2+ ions, collaborating with the environment.
期刊介绍：
The Journal of Material Cycles and Waste Management has a twofold focus: research in technical, political, and environmental problems of material cycles and waste management; and information that contributes to the development of an interdisciplinary science of material cycles and waste management. Its aim is to develop solutions and prescriptions for material cycles.
The journal publishes original articles, reviews, and invited papers from a wide range of disciplines related to material cycles and waste management.
The journal is published in cooperation with the Japan Society of Material Cycles and Waste Management (JSMCWM) and the Korea Society of Waste Management (KSWM).
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