铝生产用阳极膏的消耗量

IF 0.6 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Russian Journal of Non-Ferrous Metals Pub Date : 2022-07-05 DOI:10.3103/S106782122203004X
A. A. Drizhenko, S. V. Datsyura, A. S. Yasinsky
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引用次数: 0

摘要

在俄罗斯,大多数铝冶炼厂都配备了带有自焙阳极的电解槽,因为阳极材料在铝成本中的比例从8%到20%不等,因此减少阳极膏消耗的任务与此相关。要解决这个问题,有必要确定需要阳极膏。铝工业企业使用的阳极膏比消耗量计算方法存在较大误差。本文讨论了该方法的主要误差,说明了计算阳极膏体流量的各个阶段,评价了计算的充分性,并提出了改进的建议。总的来说,所考虑的方法充分反映了碳消耗的过程;然而,计算的最终结果可能与实际结果有很大差异。为简化计算而取的常数,实际上在电解过程中会发生变化,从而导致最终计算结果发生显著变化。例如,当CO的分数从0.45增加到0.5时,阳极膏的消耗量减少了15.3 kg/t Al。同时,我们知道,随着阳极效应的开始,阳极气体的组成发生了急剧变化:CO2的分数减少,CO的分数增加。在夏季,在较高的环境温度下,随着表面温度的升高,汽化沥青的比例和阳极的比例都升高。后者变为0.25会导致阳极膏消耗增加6.6 kg/t铝。同样的情况也适用于空气氧化。减压电池的数量可能会增加,这将增加碳消耗。有必要注意影响阳极质量的因素。错误选择的粒度分布或磨损的设备会显著降低阳极的质量,导致碳消耗增加。为了正确地考虑到一氧化碳形成的特殊性,有必要对计算进行调整。
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Consumption of Anode Paste for Aluminum Production

In Russia, most aluminum smelters are equipped with cells with self-baking anodes for which the task of reducing of anode paste consumption is relevant, since the fraction of anode materials in the cost of aluminum varies from 8 to 20%. To solve this problem, it is necessary to determine the need for anode paste. The method for calculating the specific anode paste consumption used at the enterprises of the aluminum industry has a large error. The article discusses the main errors of this technique, shows the stages of calculating the flow rate of the anode paste, assesses the adequacy of the calculations, and gives recommendations for improving the technique. In general, the considered methodology adequately reflects the processes of carbon consumption; however, the final result of the calculations may differ significantly from the real one. The values taken constant to simplify the calculation, in fact, can change during the electrolysis, which leads to a significant change in the final result of the calculations. For example, an increase in the fraction of CO2 from 0.45 to 0.5 leads to a decrease in the anode paste consumption by 15.3 kg/t Al. At the same time, it is known that, with the onset of the anode effect, the composition of the anode gases changes sharply: the fraction of CO2 decreases, and the fraction of CO increases. In summer, at high ambient temperatures, both the proportion of vaporized pitch and the proportion of anodes with an increased surface temperature rise. A change in the latter to 0.25 leads to an increase in anode paste consumption by 6.6 kg/t Al. The same applies to oxidation in air. The number of depressurized cells may increase, which will increase the carbon consumption. It is necessary to pay attention to the factors affecting the quality of the anode. Incorrectly selected particle size distribution or worn equipment can significantly degrade the quality of the anode and lead to an increase in carbon consumption. To correctly take into account the peculiarities of the formation of carbon monoxide, it is necessary to make adjustments to the calculation.

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来源期刊
Russian Journal of Non-Ferrous Metals
Russian Journal of Non-Ferrous Metals METALLURGY & METALLURGICAL ENGINEERING-
CiteScore
1.90
自引率
12.50%
发文量
59
审稿时长
3 months
期刊介绍: Russian Journal of Non-Ferrous Metals is a journal the main goal of which is to achieve new knowledge in the following topics: extraction metallurgy, hydro- and pirometallurgy, casting, plastic deformation, metallography and heat treatment, powder metallurgy and composites, self-propagating high-temperature synthesis, surface engineering and advanced protected coatings, environments, and energy capacity in non-ferrous metallurgy.
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