空果束(EFB)中水凝胶和干凝胶吸附剂的比较

A. Alias, D. Qarizada, N. Malik, N. Noraini, Z. A. Rashid
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引用次数: 0

摘要

本文主要研究了以EFB为原料合成水凝胶基和干凝胶基吸附剂的比较。以丙烯酰胺(AAm)为单体,N,N’-亚甲基双丙烯酰胺(MBA)为交联剂,过硫酸铵(APS)为引发剂,以EFB生物炭为原料,采用海藻酸钠、,碳酸钙(CaCO3)和葡萄糖酸-Δ内酯(GDL)。从获得的藻酸盐水凝胶中,通过烘箱干燥法合成了干凝胶。然后,基于扫描电子显微镜(SEM)、BrunauerEmmettTeller(BET)、傅立叶变换红外光谱(FTIR)和热重分析(TGA)的表征分析,对基于EFB的水凝胶和干凝胶吸附剂进行了分析和比较,孔径更大(63.7987nm),水分含量更高(7.97%),灰分含量更低(12.55%),并且更热稳定。本研究旨在比较EFB的两种新型吸附剂Hydrogel和Xerogel的特性。两种吸附剂都显示出高毒性物质吸收,特别是EFB干凝胶。这种吸附剂与其他商业化吸附剂相当。因此,该产品可以是用于气体和废水吸附的高潜力吸附剂。这篇文章的真实性结果被发现有15%的相似性。本文的新颖之处在于比较了源自EFB的两种吸附剂,即水凝胶和干凝胶。
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Comparison of hydrogel- and xerogel-based sorbent from Empty Fruit Bunch (EFB)
This paper focuses on the synthesis and comparison of hydrogel- and xerogel-based sorbents from EFB.Hydrogels were synthesised by polymerisation of EFB biochar with acrylamide (AAm) as a monomer, N, N'-Methylenebisacrylamide (MBA) as cross-linker and ammonium persulfate (APS) as initiator, as well as by internal gelation method of sodium alginate, empty fruit bunch (EFB), calcium carbonate (CaCO3), and glucono delta-lactone (GDL). From the alginate hydrogels obtained, xerogels were synthesised via the oven-drying method. Then, EFB-based hydrogel and xerogel sorbents were analysed and compared based on characterisation analysis by using scanning electron microscopy (SEM), BrunauerEmmettTeller (BET), Fourier-Transform Infrared Spectroscopy (FTIR), and thermogravimetric analysis (TGA).The xerogel-based EFB is a better adsorbent than the hydrogel-based EFB because it has a larger pore volume (0.001449 cm3/g), larger pore size (63.7987 nm), higher moisture content (7.97%), lower ash content (12.55%), and is more thermally stable.The research is to compare two new adsorbents, namely Hydrogel and Xerogel, from EFB in terms of their characteristics.Both adsorbents show a highly toxic material uptake, especially EFB xerogel. This adsorbent is comparable with the other commercialised adsorbent. Thus, this product can be a highly potential adsorbent for gas and wastewater adsorption.The authenticity results of this article were found to be 15% similar. The novelty of this paper is to compare the two adsorbents, namely hydrogel and xerogel, that originated from EFB.
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来源期刊
Archives of materials science and engineering
Archives of materials science and engineering Materials Science-Materials Science (all)
CiteScore
2.90
自引率
0.00%
发文量
15
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