{"title":"热轧钢筋在混凝土中的腐蚀性能优化","authors":"Qinghai Zhou, Yanbin Yin, Zhiming Liu, Jiongming Zhang","doi":"10.1080/1478422X.2022.2101179","DOIUrl":null,"url":null,"abstract":"ABSTRACT To optimising the corrosion resistance mechanism of hot-rolled steel bar, the effects of different tempering temperatures and high-oxygen-rich oxidation times were studied by scanning electron microscopy, X-ray diffraction, Raman spectroscopy, electrochemical and atmospheric corrosion tests. The thickness of the oxide layer of the rebar could reach 10 μm and rarely corroded after high-oxygen-rich oxidation at 850°C for 1 s, which exhibits superior corrosion resistance. The electrochemical test results showed that the I corr value after 1 s of high-oxygen-rich oxidation at 850°C was about 0.02 mA cm−2, which was 56.4% lower than that of the heated specimen at 685°C (0.045 mA cm−2). The results of Raman spectroscopy showed that the rust layer of the heated specimen at 685°C mainly consisted of α-Fe2O3, γ-FeOOH and α-FeOOH, and the oxidised layer after 1 s of high-oxygen-rich oxidation at 850°C mainly consisted of α-Fe2O3 and Fe3O4, which maintained the original oxidised layer morphology.","PeriodicalId":10711,"journal":{"name":"Corrosion Engineering, Science and Technology","volume":"57 1","pages":"568 - 579"},"PeriodicalIF":1.5000,"publicationDate":"2022-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Optimising the corrosion performance of hot-rolled steel bar in concrete\",\"authors\":\"Qinghai Zhou, Yanbin Yin, Zhiming Liu, Jiongming Zhang\",\"doi\":\"10.1080/1478422X.2022.2101179\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"ABSTRACT To optimising the corrosion resistance mechanism of hot-rolled steel bar, the effects of different tempering temperatures and high-oxygen-rich oxidation times were studied by scanning electron microscopy, X-ray diffraction, Raman spectroscopy, electrochemical and atmospheric corrosion tests. The thickness of the oxide layer of the rebar could reach 10 μm and rarely corroded after high-oxygen-rich oxidation at 850°C for 1 s, which exhibits superior corrosion resistance. The electrochemical test results showed that the I corr value after 1 s of high-oxygen-rich oxidation at 850°C was about 0.02 mA cm−2, which was 56.4% lower than that of the heated specimen at 685°C (0.045 mA cm−2). The results of Raman spectroscopy showed that the rust layer of the heated specimen at 685°C mainly consisted of α-Fe2O3, γ-FeOOH and α-FeOOH, and the oxidised layer after 1 s of high-oxygen-rich oxidation at 850°C mainly consisted of α-Fe2O3 and Fe3O4, which maintained the original oxidised layer morphology.\",\"PeriodicalId\":10711,\"journal\":{\"name\":\"Corrosion Engineering, Science and Technology\",\"volume\":\"57 1\",\"pages\":\"568 - 579\"},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2022-07-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Corrosion Engineering, Science and Technology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1080/1478422X.2022.2101179\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Corrosion Engineering, Science and Technology","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1080/1478422X.2022.2101179","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
摘要为了优化热轧钢筋的耐腐蚀机理,通过扫描电子显微镜、X射线衍射、拉曼光谱、电化学和大气腐蚀试验,研究了不同回火温度和高富氧氧化时间对其耐腐蚀性能的影响。钢筋的氧化层厚度可达10 μm,在850°C下高富氧氧化1小时后很少腐蚀 s、 其表现出优异的耐腐蚀性。电化学测试结果表明,1 850°C下高富氧氧化的s约为0.02 mA cm−2,比685°C(0.045 mA)下加热试样的温度低56.4% cm−2)。拉曼光谱结果表明,685°C加热试样的锈层主要由α-Fe2O3、γ-FeOOH和α-FeOOH组成,1 850°C下的高富氧氧化主要由α-Fe2O3和Fe3O4组成,它们保持了原始的氧化层形态。
Optimising the corrosion performance of hot-rolled steel bar in concrete
ABSTRACT To optimising the corrosion resistance mechanism of hot-rolled steel bar, the effects of different tempering temperatures and high-oxygen-rich oxidation times were studied by scanning electron microscopy, X-ray diffraction, Raman spectroscopy, electrochemical and atmospheric corrosion tests. The thickness of the oxide layer of the rebar could reach 10 μm and rarely corroded after high-oxygen-rich oxidation at 850°C for 1 s, which exhibits superior corrosion resistance. The electrochemical test results showed that the I corr value after 1 s of high-oxygen-rich oxidation at 850°C was about 0.02 mA cm−2, which was 56.4% lower than that of the heated specimen at 685°C (0.045 mA cm−2). The results of Raman spectroscopy showed that the rust layer of the heated specimen at 685°C mainly consisted of α-Fe2O3, γ-FeOOH and α-FeOOH, and the oxidised layer after 1 s of high-oxygen-rich oxidation at 850°C mainly consisted of α-Fe2O3 and Fe3O4, which maintained the original oxidised layer morphology.
期刊介绍:
Corrosion Engineering, Science and Technology provides broad international coverage of research and practice in corrosion processes and corrosion control. Peer-reviewed contributions address all aspects of corrosion engineering and corrosion science; there is strong emphasis on effective design and materials selection to combat corrosion and the journal carries failure case studies to further knowledge in these areas.