Suba Lakshmi Madaswamy , N. Veni Keertheeswari , Asma A. Alothman , Murefah mana AL-Anazy , Khadraa N. Alqahtani , Saikh M. Wabaidur , Ragupathy Dhanusuraman
{"title":"Pd纳米粒子/聚二苯胺锚定在还原氧化石墨烯表面制备纳米复合网络:甲醇氧化的高效阳极电催化剂","authors":"Suba Lakshmi Madaswamy , N. Veni Keertheeswari , Asma A. Alothman , Murefah mana AL-Anazy , Khadraa N. Alqahtani , Saikh M. Wabaidur , Ragupathy Dhanusuraman","doi":"10.1016/j.aiepr.2021.08.001","DOIUrl":null,"url":null,"abstract":"<div><p>Direct methanol fuel cells (DMFCs) are an essential aspect of electricity and fuel concerns<strong>.</strong> Herein, we report a new combination of Palladium nanoparticles anchored on polydiphenylamine with reduced graphene oxide network (rGO/PDPA/Pd) nanohybrid synthesized via an in-situ chemical strategy. The rGO/PDPA/Pd electrocatalyst shows excellent electrocatalytic activity, lower oxidation potential (−0.1 V), improved current density (2.85 mA/cm<sup>2</sup>), excellent cyclic stability (94%), and longevity (1200 s) towards methanol oxidation reaction (MOR) in the alkaline medium, when compared to commercial Pd/C electrocatalyst. Significantly, the forward oxidation peak potential of rGO/PDPA/Pd electrocatalyst was shifted negatively by 110 mV as compared to commercial Pd/C electrocatalyst. These results suggest that rGO/PDPA/Pd electrocatalyst is considered as an effective anode catalyst for DMFCs.</p></div>","PeriodicalId":7186,"journal":{"name":"Advanced Industrial and Engineering Polymer Research","volume":"5 1","pages":"Pages 18-25"},"PeriodicalIF":12.0000,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2542504821000580/pdfft?md5=6a54836b2385479b6eb12149bffd91f8&pid=1-s2.0-S2542504821000580-main.pdf","citationCount":"11","resultStr":"{\"title\":\"Fabrication of nanocomposite networks using Pd nanoparticles/Polydiphenylamine anchored on the surface of reduced graphene oxide: An efficient anode electrocatalyst for oxidation of methanol\",\"authors\":\"Suba Lakshmi Madaswamy , N. Veni Keertheeswari , Asma A. Alothman , Murefah mana AL-Anazy , Khadraa N. Alqahtani , Saikh M. Wabaidur , Ragupathy Dhanusuraman\",\"doi\":\"10.1016/j.aiepr.2021.08.001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Direct methanol fuel cells (DMFCs) are an essential aspect of electricity and fuel concerns<strong>.</strong> Herein, we report a new combination of Palladium nanoparticles anchored on polydiphenylamine with reduced graphene oxide network (rGO/PDPA/Pd) nanohybrid synthesized via an in-situ chemical strategy. The rGO/PDPA/Pd electrocatalyst shows excellent electrocatalytic activity, lower oxidation potential (−0.1 V), improved current density (2.85 mA/cm<sup>2</sup>), excellent cyclic stability (94%), and longevity (1200 s) towards methanol oxidation reaction (MOR) in the alkaline medium, when compared to commercial Pd/C electrocatalyst. Significantly, the forward oxidation peak potential of rGO/PDPA/Pd electrocatalyst was shifted negatively by 110 mV as compared to commercial Pd/C electrocatalyst. These results suggest that rGO/PDPA/Pd electrocatalyst is considered as an effective anode catalyst for DMFCs.</p></div>\",\"PeriodicalId\":7186,\"journal\":{\"name\":\"Advanced Industrial and Engineering Polymer Research\",\"volume\":\"5 1\",\"pages\":\"Pages 18-25\"},\"PeriodicalIF\":12.0000,\"publicationDate\":\"2022-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2542504821000580/pdfft?md5=6a54836b2385479b6eb12149bffd91f8&pid=1-s2.0-S2542504821000580-main.pdf\",\"citationCount\":\"11\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Industrial and Engineering Polymer Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2542504821000580\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2021/10/23 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, COMPOSITES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Industrial and Engineering Polymer Research","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2542504821000580","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2021/10/23 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
Fabrication of nanocomposite networks using Pd nanoparticles/Polydiphenylamine anchored on the surface of reduced graphene oxide: An efficient anode electrocatalyst for oxidation of methanol
Direct methanol fuel cells (DMFCs) are an essential aspect of electricity and fuel concerns. Herein, we report a new combination of Palladium nanoparticles anchored on polydiphenylamine with reduced graphene oxide network (rGO/PDPA/Pd) nanohybrid synthesized via an in-situ chemical strategy. The rGO/PDPA/Pd electrocatalyst shows excellent electrocatalytic activity, lower oxidation potential (−0.1 V), improved current density (2.85 mA/cm2), excellent cyclic stability (94%), and longevity (1200 s) towards methanol oxidation reaction (MOR) in the alkaline medium, when compared to commercial Pd/C electrocatalyst. Significantly, the forward oxidation peak potential of rGO/PDPA/Pd electrocatalyst was shifted negatively by 110 mV as compared to commercial Pd/C electrocatalyst. These results suggest that rGO/PDPA/Pd electrocatalyst is considered as an effective anode catalyst for DMFCs.
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