壳聚糖/尼龙6/聚氨酯共混物的合成、表征和性能用于从水溶液中去除铬(VI)和铅(II)离子以增强动力学吸附研究

IF 4.3 4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Water Reuse Pub Date : 2023-06-07 DOI:10.2166/wrd.2023.019
S. Jayakumar, S. Sudarsan, B. Sridhar, E. Parthiban, A. Jerwin Prabu, S. Jha
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引用次数: 0

摘要

吸附对于去除污染溶液介质中的Cr6+和Pb2+离子至关重要。研究了由壳聚糖、尼龙6和聚氨酯泡沫(CS/Ny6/PUF)按2:1:1的比例共混而成的三元共混物。由于在酸性和碱性介质中的不溶性,这些混合物被用作吸附剂。通过改变pH、接触时间和吸附剂用量来分析吸附效果。金属离子的最大吸收已经在pH范围5中表现出来。平衡吸附统计表明,吸附等温线符合Freundlich模型。吸附动力学参数表明,铬的吸附表现出拟二级反应和铅的拟一级反应。
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Synthesis, characterization, and performance of chitosan/nylon 6/polyurethane blend for the removal of chromium (VI) and lead (II) ions from aqueous solutions for enhanced kinetic adsorption studies
Adsorption is vital for the elimination of Cr6+ and Pb2+ ions in the contaminated solution medium. A ternary blend made up of chitosan, nylon 6 and polyurethane foam (CS/Ny 6/PUF) blend in the ratio of 2:1:1 has been investigated. These blends are used as an adsorbent due to the insoluble nature in acidic and basic medium. The adsorption efficacy was analyzed by modifying pH, contact time, and adsorbent dosage. The maximum uptake of metal ions has been exhibited in the pH range 5. An equilibrium adsorption statistic indicated that adsorption isotherm follows the Freundlich model. The adsorption kinetic parameters specified that the adsorption of chromium has shown pseudo-second-order and lead pseudo-first-order reaction.
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来源期刊
Water Reuse
Water Reuse Multiple-
CiteScore
6.20
自引率
8.90%
发文量
0
审稿时长
7 weeks
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