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Removal of Tellurium(IV) from environmental aquatic systems using metal-organic framework material MIL-100(Fe) 利用金属有机框架材料 MIL-100(Fe) 去除环境水生系统中的碲(IV)
IF 4.5 4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-01-09 DOI: 10.2166/wrd.2024.118
Yiru Huang, Youyou Li, Qingwei Zhong, Cheng Luo
Metal-organic framework (MOF) materials, characterized by their porosity and large specific surface areas, exhibit excellent adsorption properties. With the aim of removing Te(IV) from environmental aquatic systems, this study is the first to propose the use of MIL-100(Fe). The material reveals a strong adsorption capacity for Te(IV), with maximum adsorption of 531.9 mg/g, superior to other adsorbent materials. Adsorption isotherm models and kinetic models indicate that the adsorption process of Te(IV) primarily involves monolayer chemical adsorption. According to the thermodynamic parameters of Te(IV) adsorption on MIL-100(Fe), the adsorption reaction is endothermic. The experiment individually examined factors affecting the material's adsorption performance, including adsorbent dose, initial concentration of Te(IV), pH, adsorption time, and coexisting ions. Even under high ion strength conditions and high concentrations of coexisting ions, the material's adsorption efficiency for Te(IV) still reached over 95%. The material has been successfully applied to remove Te(IV) from lake water, river water, and seawater, yielding satisfactory results. Due to the high salinity and ionic strength of the solution, the removal efficiency of Te(IV) in the seawater matrix was slightly lower than that in freshwater (river and lake water). Thus, this material shows promise for the removal of Te(IV) from complex aquatic systems.
金属有机框架(MOF)材料具有多孔性和大比表面积的特点,具有优异的吸附性能。为了去除环境水生系统中的 Te(IV),本研究首次提出使用 MIL-100(Fe)。该材料对 Te(IV) 具有很强的吸附能力,最大吸附量为 531.9 mg/g,优于其他吸附材料。吸附等温线模型和动力学模型表明,Te(IV)的吸附过程主要是单层化学吸附。根据 Te(IV)在 MIL-100(Fe)上吸附的热力学参数,吸附反应是内热的。实验分别考察了影响材料吸附性能的因素,包括吸附剂剂量、Te(IV) 初始浓度、pH 值、吸附时间和共存离子。即使在高离子强度和高浓度共存离子条件下,该材料对 Te(IV)的吸附效率仍达到 95% 以上。该材料已成功应用于去除湖水、河水和海水中的 Te(IV),并取得了令人满意的效果。由于溶液的盐度和离子强度较高,海水基质对 Te(IV) 的去除率略低于淡水(河水和湖水)。因此,这种材料有望从复杂的水生系统中去除 Te(IV)。
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引用次数: 0
Effectiveness and health risk assessment of drinking water from different sources treated by local household water treatment methods in Bamenda, Cameroon 喀麦隆巴门达采用当地家庭水处理方法处理不同水源饮用水的效果和健康风险评估
IF 4.5 4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-12-29 DOI: 10.2166/wrd.2023.120
Therese Ncheuveu Nkwatoh, Paul Oto Beseka Itor, Benard Mingo Yakum
This study accessed the efficiency and health risks of drinking water from different sources treated by filtration, boiling, chlorination, flocculation, and solar disinfection. The microbial quality of 45 treated water samples from boreholes, wells, and pipe-borne water was analyzed to determine treatment effectiveness and to quantify risk using quantitative microbial risk assessment. The effectiveness of each treatment method was a function of sampling sources (p < 0.05) and location (p < 0.10), chlorination and boiling being the most efficient methods (100%). Shiegella in well water samples treated by filtration and flocculation had the highest daily infection risk of 69.5 × 10−1 and 67.5 × 10−1 pppd. The annual risk of infection from Salmonella, Shigella, and Staphylococcus ranged from 7.8 × 10−1 to 1.00 pppy, exceeding the U.S. EPA annual infection benchmark (≤10−4 pppy). Salmonella, Shigella, and Staphylococcus had the highest risk of illness of 4.50 × 10−1, 3.30 × 10−1, and 9.80 × 10−1, respectively. All disease burden values exceeded the WHO disease burden benchmark (≤10−6 DALYs/pppy), with Staphylococcus and Salmonella contributing the highest disease burden of 4.71 × 10−2 and 2.13 × 10−2, DALYs/pppy. Therefore, boiling and chlorination are the best disinfection methods for the pathogens tested.
本研究调查了不同水源的饮用水经过滤、煮沸、加氯、絮凝和太阳能消毒处理后的效率和健康风险。研究分析了 45 个经过处理的井水、井水和管道水样本的微生物质量,以确定处理效果,并利用微生物定量风险评估对风险进行量化。每种处理方法的有效性都与采样来源(p < 0.05)和地点(p < 0.10)有关,氯化和煮沸是最有效的方法(100%)。经过滤和絮凝处理的井水样本中的谢杰氏菌的日感染风险最高,分别为 69.5 × 10-1 和 67.5 × 10-1 pppd。沙门氏菌、志贺氏菌和葡萄球菌的年感染风险从 7.8 × 10-1 到 1.00 pppy 不等,超过了美国环保局的年感染基准(≤10-4 pppy)。沙门氏菌、志贺氏菌和葡萄球菌的患病风险最高,分别为 4.50 × 10-1、3.30 × 10-1 和 9.80 × 10-1。所有疾病负担值都超过了世界卫生组织的疾病负担基准(≤10-6 DALYs/pppy),其中葡萄球菌和沙门氏菌造成的疾病负担最高,分别为 4.71 × 10-2 和 2.13 × 10-2,DALYs/pppy。因此,煮沸和加氯是针对测试病原体的最佳消毒方法。
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引用次数: 0
Adsorption efficiency of biochar produced by aquaculture by-products for removing geosmin in aquaculture environment 利用水产养殖副产品生产的生物炭在去除水产养殖环境中的地奥司明中的吸附效率
IF 4.5 4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-12-12 DOI: 10.2166/wrd.2023.129
Yadi Cui, Xi Chen, Chompoonuch Pitakrattanawong, Xiaolu Du, Liping Qiu, Huimin Xu, Jiazhang Chen, Shunlong Meng, Limin Fan, Chao Song
Aquaculture produces numerous by-products like aquatic plants, algae, and nutrient-enriched sediment annually, which are often discarded as waste, are not environmentally friendly, and are harmful to the environment. In this study, aquaculture by-products were utilized to prepare moss biochar at 500, 700, and 800 °C (BC500, BC700, and BC800, respectively); Elodea biochar (WBC800) at 800 °C; and sediment biochar (SBC800) at 800 °C. Characterization and experimental results showed that BC800 had the best adsorption effect on geosmin (GSM) under the same conditions; when using BC800 to treat GSM solution with a pH of 7, the adsorption efficiency of GSM was high (97.08%) under the conditions of dosage of 1.0 g, temperature of 25 °C, and adsorption time of 2 min. Adsorption is a multimolecular layer process that involves both physical aspects of porous adsorption and connections between chemical bonds. Biochar, derived from aquaculture by-products, is utilized to eliminate odorous substances in aquaculture environments, thereby promoting resource recycling.
水产养殖每年会产生大量副产品,如水生植物、藻类和营养丰富的沉积物,这些副产品通常被作为废物丢弃,不环保,对环境有害。本研究利用水产养殖副产品制备了温度分别为 500、700 和 800 ℃ 的苔藓生物炭(BC500、BC700 和 BC800)、温度为 800 ℃ 的裙带菜生物炭(WBC800)和温度为 800 ℃ 的沉积物生物炭(SBC800)。表征和实验结果表明,在相同条件下,BC800 对地黄素(GSM)的吸附效果最好;用 BC800 处理 pH 值为 7 的地黄素溶液时,在用量为 1.0 克、温度为 25 ℃、吸附时间为 2 分钟的条件下,地黄素的吸附效率很高(97.08%)。吸附是一个多分子层过程,涉及多孔吸附的物理方面和化学键之间的联系。生物炭取自水产养殖副产品,可用于消除水产养殖环境中的异味物质,从而促进资源循环利用。
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引用次数: 0
Enhancing stormwater treatment through ultrafiltration: impact of cleaning chemicals and backwash duration on membrane efficiency 通过超滤加强雨水处理:清洗化学品和反冲洗持续时间对膜效率的影响
IF 4.5 4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-11-20 DOI: 10.2166/wrd.2023.106
Saida Kaykhaii, I. Herrmann, A. Hedström, K. Nordqvist, Ingemar Heidfors, M. Viklander
The effect of chemical cleaning and regular backwashing on the efficiency of an ultrafiltration membrane fouled during stormwater treatment was studied. Increasing backwash time from 30 to 60 s resulted in an increase in productivity by 20%. However, the productivity was highest when a backwash time of 45 s was used (3% higher than using 60 s). Chemical cleaning was carried out using an alkaline solution (NaOH with or without NaOCl) followed by acid washing with HCl. The addition of NaOCl to the cleaning chemical did not significantly increase the efficiency of chemical cleaning, and the average pure water permeability increase was 97 ± 13 LMH bar−1 after chemical cleaning with NaOH followed by HCl and 117 ± 15 LMH bar−1 after chemical cleaning with NaOH + NaOCl followed by HCl, on average. In addition, reversibility after chemical cleaning was 96 ± 67%, on average. The result from scanning electron microscopy showed that at the end of the experiments, inorganic foulants existed in both the inner layer (feed side) and the outer layer (permeate side) of the membrane.
研究了化学清洗和定期反冲洗对雨水处理过程中结垢的超滤膜效率的影响。反冲洗时间从 30 秒增加到 60 秒,生产率提高了 20%。然而,当反洗时间为 45 秒时,生产率最高(比 60 秒时高出 3%)。使用碱性溶液(含或不含 NaOCl 的 NaOH)进行化学清洗,然后使用 HCl 进行酸洗。在清洗剂中加入 NaOCl 并没有明显提高化学清洗的效率,在使用 NaOH 进行化学清洗后再使用 HCl 进行清洗,纯水渗透率平均提高了 97 ± 13 LMH bar-1,在使用 NaOH + NaOCl 进行化学清洗后再使用 HCl 进行清洗,纯水渗透率平均提高了 117 ± 15 LMH bar-1。此外,化学清洗后的可逆性平均为 96 ± 67%。扫描电子显微镜的结果表明,在实验结束时,膜的内层(进水侧)和外层(渗透侧)都存在无机污垢。
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引用次数: 0
cutting-edge research on the action plan for the prevention and control of emerging contaminants in China 中国新兴污染物防治行动计划的前沿研究
4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-11-10 DOI: 10.2166/wrd.2023.001
Ye Du, Hai-xiang Li, Yun Lu, Dong-bin Wei, Wen-long Wang
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引用次数: 0
Wastewater governance in the upstream catchment of the Awash Basin, Ethiopia: challenges and opportunities for better accountability 埃塞俄比亚阿瓦什盆地上游集水区的废水治理:改善问责制的挑战与机遇
4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-10-30 DOI: 10.2166/wrd.2023.077
Yosef Abebe, Mulugeta Gashaw, Asenake Kefale, Tim Brewer
Abstract With the growing competition for water, demand for food, and the decline of freshwater resources, wastewater and polluted river waters have been increasingly used for agriculture in Ethiopia. The findings of this study show that untreated wastewater discharged from industries into the environment has been polluting rivers and the surrounding environment. Regulatory bodies did little to enforce rules, regulations, and directives provided for the regulation of wastewater. This paper examines the factors that explain weaknesses with respect to the accountability of institutions meant for wastewater governance. In doing so, it discusses task overlaps, corruption, and the absence of environmental courts that significantly affect environmental protection activities. The study found that due to poor implementation of laws and regulations, and lack of relevant information, including poor evidence of the pollution load, enforcement activities are under a great challenge. The paper concludes that urban agriculture has been expanding without concern for its negative health and socioeconomic impacts. The positive economic impacts of wastewater agriculture also need to be reassessed and improved as one livelihood option for the farming communities and calls for awareness creation and other measures to fully understand the existing benefits and impacts of wastewater on human health and the environment.
随着水资源竞争的加剧,对食物的需求以及淡水资源的减少,埃塞俄比亚越来越多地将废水和受污染的河水用于农业。本研究结果表明,工业排放到环境中的未经处理的废水已经污染了河流和周围环境。监管机构在执行废水监管规定的规则、条例和指令方面做得很少。本文考察了解释废水治理机构问责制方面的弱点的因素。在此过程中,它讨论了任务重叠、腐败和缺乏环境法院等严重影响环境保护活动的问题。研究发现,由于法律法规执行不力,以及缺乏相关信息,包括污染负荷证据不足,执法活动面临很大挑战。本文的结论是,城市农业一直在扩张,而没有考虑其对健康和社会经济的负面影响。废水农业的积极经济影响也需要重新评估和改善,作为农业社区的一种生计选择,并呼吁提高认识和采取其他措施,以充分了解废水对人类健康和环境的现有好处和影响。
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引用次数: 0
Tertiary treatment using ultrafiltration in an existing sewage treatment plant for industrial reuse – a modelling approach using an artificial neural network with uncertainty estimation 在现有的工业回用污水处理厂使用超滤进行三级处理-一种使用不确定性估计的人工神经网络建模方法
4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-10-19 DOI: 10.2166/wrd.2023.179
D. Ramkumar, Vinayakam Jothiprakash
Abstract Navi Mumbai Municipal Corporation of Maharashtra state, India, unified a tertiary treatment plant (TTP) of 20 million litres per day (MLD) capacity with ultrafiltration technology in an existing Koparkhairane sewage treatment plant (STP) for producing effluent quality usable for industrial purposes. As prior art, an artificial neural network-genetic algorithm (ANN-GA) along with uncertainty estimation using prediction interval is employed to model secondary treated effluent (STE) flow rate (QT) and other quality parameters such as biochemical oxygen demand, chemical oxygen demand, and total suspended solids (TSS) to conclude the reliability of the range in which the input available to TTP. ANN-GA model provides a coefficient of determination above 0.90 for all STE parameters modelled other than TSS. Inferring that a good quantity and quality of 20 MLD STP treated water is currently available, where a decreasing trend of QT is also noticed and highlighted. Further, the Wilcoxon signed-rank test on the quality parameter of effluent TTP for industrial reuse standard infers TSS shows infringement during the initial period but started adhering to standards over time. The research delineates at the outset of exploring water reuse policy in India, emphasizing Maharashtra state, modelling STE using ANN-GA and performance evaluation of TTP.
印度马哈拉施特拉邦的新孟买市政公司在现有的Koparkhairane污水处理厂(STP)中统一了一个每天2000万升(MLD)能力的三级处理厂(TTP),用于生产可用于工业目的的污水。作为现有技术,采用人工神经网络遗传算法(ANN-GA)以及使用预测区间的不确定性估计对二级处理出水(STE)流量(QT)和其他质量参数(如生化需氧量、化学需氧量和总悬浮固体(TSS))进行建模,以得出TTP可用输入范围的可靠性。ANN-GA模型除TSS外,所有STE参数的确定系数均在0.90以上。推断目前有20个MLD STP处理水的数量和质量都很好,其中QT也有下降的趋势。进一步,对工业回用标准出水TTP的质量参数进行Wilcoxon sign -rank检验,得出TSS在初始阶段表现为侵权,但随着时间的推移开始遵守标准。该研究首先描述了探索印度的水再利用政策,重点是马哈拉施特拉邦,使用ANN-GA建模STE和TTP的绩效评估。
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引用次数: 0
Experimental and theoretical analysis of solar still with solar pond for enhancing the performance of sea water desalination 太阳池式太阳能蒸馏器提高海水淡化性能的实验与理论分析
4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-10-18 DOI: 10.2166/wrd.2023.102
M. Yuvaperiyasamy, N. Senthilkumar, B. Deepanraj
Abstract In a practical scenario, only a modest amount of distilled water can be generated each day by a basic solar still with a single basin. Fin-type solar ponds, fin-type solar stills, and integrated fin-type solar stills with finned ponds are investigated. The theoretic performance and experimental studies on the proposed systems were carried out in Pongalur near Tirupur (10.9729° N, 77.3698° E), a region with a latitude of 10° north. Single basin solar still (SBSS), single basin solar still with fin, single basin solar still with pond, single basin solar still with finned pond, and integrated single basin fin-type solar still with a finned solar pond were developed. Adding fins to the small solar pond enhanced the thermal performance of SBSS, by increasing the daily water collection. The pace at which heat is transmitted from the basin to water has risen due to the fins. According to this study, the amount of water collected by single basin solar still with fin, single basin solar still with finned pond, and integrated single basin solar still with fins and finned pond grew by 46, 48, and 52% for each of these systems.
在一个实际的场景中,一个基本的太阳能蒸馏器每天只能产生少量的蒸馏水。研究了鳍式太阳能池、鳍式太阳能蒸馏器和鳍式太阳能蒸馏器与鳍式太阳能蒸馏器的集成。该系统的理论性能和实验研究在Tirupur附近的Pongalur(10.9729°N, 77.3698°E)进行,该地区纬度为北纬10°。开发了单盆式太阳能蒸馏器、单盆带鳍式太阳能蒸馏器、单盆带池式太阳能蒸馏器、单盆带鳍式太阳能蒸馏器、单盆带鳍式太阳能蒸馏器和一体化单盆鳍式太阳能蒸馏器。在小型太阳能池中添加翅片,通过增加日集水量来增强SBSS的热性能。由于鳍片的作用,热量从盆地传递到水中的速度加快了。研究结果表明,单盆带翅片太阳能蓄热器、单盆带翅片池太阳能蓄热器和单盆带翅片池太阳能蓄热器集水量分别增长了46%、48%和52%。
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引用次数: 1
Water quality for agricultural irrigation produced by two municipal sewage treatment plants in Santiago Island-Cape Verde: assessment of chemical parameters and pharmaceutical residues 圣地亚哥岛-佛得角两个城市污水处理厂生产的农业灌溉用水质量:化学参数和药物残留的评估
4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-10-17 DOI: 10.2166/wrd.2023.094
Maria dos Anjos de Jesus Barros Monteiro Lopes, Rayco Guedes-Alonso, Vanessa Mendoza-Grimón, Sarah Montesdeoca-Esponda, Juan Ramon Fernández-Vera, Zoraida Sosa-Ferrera, José Juan Santana-Rodríguez, Maria del Pino Palacios-Díaz
Abstract Cape Verde, a West Africa Island country, is exposed to climate change effect. An effective way of reducing its poverty and achieving food security is to provide its agricultural sector with water. The purpose of this study is to monitor treated water quality to ensure that any pollutants are below the limits set to ensure the safety and sustainability of reuse because only 10% of its treated wastewater is reused. For the first time on Cape Verde islands, besides chemical quality, the occurrence of 11 pharmaceutical compounds (PhC) in the influent and effluent of two natural wastewater treatment plants (WWTPs) was monitored to assess the effectiveness of the treatment technologies and removal efficiencies of these pollutants. Of the 11 target PhC, nine were detected in influent samples within the ng·L−1 to μg·L−1 range. Lower concentrations were detected in one WWTP vs. the other. Nevertheless, the removal efficiencies for most compounds were similar in both WWTPs: within the ranges of 82–92% for beta-blockers, 48–99% for stimulants and 44–95% for nonsteroidal anti-inflammatories, while carbamazepine (anticonvulsant) concentrations increased in effluents. WWTPs produce water that meets water quality standards for irrigation if a properly designed and managed reusing system is adopted.
佛得角是西非的一个岛国,受到气候变化的影响。减少其贫困和实现粮食安全的一个有效方法是向其农业部门提供水。本研究的目的是监测处理过的水质,以确保任何污染物低于为确保再利用的安全性和可持续性而设定的限制,因为只有10%的处理过的废水被再利用。在佛得角群岛,除化学质量外,还首次监测了两个天然废水处理厂的进、流出物中11种药物化合物的出现情况,以评估处理技术的有效性和对这些污染物的去除效率。在11种目标ph中,有9种在ng·L−1 ~ μg·L−1范围内检测到。在一个污水处理厂中检测到的浓度低于另一个。然而,在两种污水处理方案中,大多数化合物的去除效率相似:受体阻滞剂在82-92%的范围内,兴奋剂在48-99%的范围内,非甾体类抗炎药在44-95%的范围内,而卡马西平(抗惊厥药)浓度在排出物中增加。如果采用设计和管理得当的再利用系统,污水处理厂生产的水就能达到灌溉用水的质量标准。
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引用次数: 0
Magnetic treatment of irrigation water and its effect on French bean (Phaseolus vulgaris) 灌溉水的磁处理及其对豆荚的影响
4区 环境科学与生态学 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2023-10-12 DOI: 10.2166/wrd.2023.064
Gottam Kishore, Ranjay Kumar Singh, C. K. Saxena, Nadhir Al-Ansari, Dinesh Kumar Vishwakarma, Salim Heddam
Abstract Magnetic water treatment (magnetic treatment device (MTD)) has long been a contentious procedure for domestic water treatment. This study examines the pros and cons of using different water types with and without a magnetic field treatment for growing French bean crop irrigation. The MTD used in this experiment works by ionizing the dissolved solid using a cathode and anode, electrolysing water using a dynamic pulse current at 50 kHz, and energizing the cations using a 7,000 Gauss magnet. The MTD of normal, waste and saline water enhanced the yield by 12.7, 16.9, and 20.07% over their respective control plots. Contrarily, seed protein (22.52 g/100 g), vitamin A (687.09 IU), potassium (212.44 mg/100 g), vitamin K (14.32 mg/100 g), and calcium (39.93 mg/100 g) reached their peak values when French bean plants were irrigated by magnetically treated wastewater. Na concentration in pods was significantly reduced when 3,000 mg/L of magnetically treated saline water was used to irrigate French bean plants. The MTD of irrigation water has also improved N and K desorption from colloidal soil complexes, which significantly helped make these two elements easily available to the plants and promoting better plant growth and yield. Overall, using the MTD, the overall characteristics of French bean were improved.
摘要磁性水处理(Magnetic treatment device,简称MTD)一直是生活水处理中存在争议的一种方法。本研究考察了使用不同类型的水进行磁场处理和不进行磁场处理对种植法国豆作物灌溉的利弊。在这个实验中使用的MTD是通过使用阴极和阳极电离溶解的固体,使用50千赫的动态脉冲电流电解水,并使用7,000高斯磁铁激励阳离子来工作的。普通水、废水和咸水的MTD分别比对照增产12.7%、16.9%和20.07%。与此相反,经磁处理后的废水灌溉后,种子蛋白质(22.52 g/100 g)、维生素A (687.09 IU)、钾(212.44 mg/100 g)、维生素K (14.32 mg/100 g)和钙(39.93 mg/100 g)含量最高。用3000mg /L经磁处理的盐水灌溉豆荚,豆荚内钠浓度显著降低。灌溉水的MTD还促进了胶体土壤复合体对N和K的解吸,使植物更容易获得这两种元素,促进了植物的生长和产量。总的来说,使用MTD后,法国豆的综合性状得到了改善。
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引用次数: 0
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