Biswajit Chowdhury, Anastasia A. Zvinchuk, Rinat R. Aysin, Ekaterina A. Khakina, Polina V. Cherkasova, Sergey E. Lyubimov
{"title":"胺碘加合物作为环氧化物和CO2合成有机碳酸盐的简单有效催化剂","authors":"Biswajit Chowdhury, Anastasia A. Zvinchuk, Rinat R. Aysin, Ekaterina A. Khakina, Polina V. Cherkasova, Sergey E. Lyubimov","doi":"10.1007/s10563-021-09341-9","DOIUrl":null,"url":null,"abstract":"<div><p>New catalysts prepared by simple mixing of molecular iodine and inexpensive monodonor amines can efficiently catalyze the coupling of CO<sub>2</sub> with different epoxides at moderate temperatures (60–90 °C), pressures (10–56 atm) and low (0.25–0.5 mol %) catalytic loading. The molecular systems can be considered as the simplest and most inexpensive catalyst for the reactions.</p><h3>Graphic Abstract</h3>\n <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\n </div>","PeriodicalId":509,"journal":{"name":"Catalysis Surveys from Asia","volume":"25 4","pages":"419 - 423"},"PeriodicalIF":2.1000,"publicationDate":"2021-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":"{\"title\":\"Amine-Iodine Adducts as Simple but Effective Catalysts for the Synthesis of Organic Carbonates from Epoxides and CO2\",\"authors\":\"Biswajit Chowdhury, Anastasia A. Zvinchuk, Rinat R. Aysin, Ekaterina A. Khakina, Polina V. Cherkasova, Sergey E. Lyubimov\",\"doi\":\"10.1007/s10563-021-09341-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>New catalysts prepared by simple mixing of molecular iodine and inexpensive monodonor amines can efficiently catalyze the coupling of CO<sub>2</sub> with different epoxides at moderate temperatures (60–90 °C), pressures (10–56 atm) and low (0.25–0.5 mol %) catalytic loading. The molecular systems can be considered as the simplest and most inexpensive catalyst for the reactions.</p><h3>Graphic Abstract</h3>\\n <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\\n </div>\",\"PeriodicalId\":509,\"journal\":{\"name\":\"Catalysis Surveys from Asia\",\"volume\":\"25 4\",\"pages\":\"419 - 423\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2021-08-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Surveys from Asia\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10563-021-09341-9\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Surveys from Asia","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10563-021-09341-9","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Amine-Iodine Adducts as Simple but Effective Catalysts for the Synthesis of Organic Carbonates from Epoxides and CO2
New catalysts prepared by simple mixing of molecular iodine and inexpensive monodonor amines can efficiently catalyze the coupling of CO2 with different epoxides at moderate temperatures (60–90 °C), pressures (10–56 atm) and low (0.25–0.5 mol %) catalytic loading. The molecular systems can be considered as the simplest and most inexpensive catalyst for the reactions.
期刊介绍:
Early dissemination of important findings from Asia which may lead to new concepts in catalyst design is the main aim of this journal. Rapid, invited, short reviews and perspectives from academia and industry will constitute the major part of Catalysis Surveys from Asia . Surveys of recent progress and activities in catalytic science and technology and related areas in Asia will be covered regularly as well. We would appreciate critical comments from colleagues throughout the world about articles in Catalysis Surveys from Asia . If requested and thought appropriate, the comments will be included in the journal. We will be very happy if this journal stimulates global communication between scientists and engineers in the world of catalysis.