纳米材料随尺寸和形状变化的热物理行为

IF 0.9 Q4 THERMODYNAMICS International Journal of Thermodynamics Pub Date : 2021-02-28 DOI:10.5541/IJOT.869865
Ratan Lal Jaiswal, B. K. Pandey, Dishani Mishra, Huda Fatma
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引用次数: 5

摘要

近十年来,纳米材料的热弹性特性一直是研究人员非常感兴趣的问题,但准确预测纳米材料的热弹性特性仍然是一个巨大的挑战。本文研究了不同形状纳米材料在考虑填充系数影响下的低维固体体积热膨胀系数和杨氏模量随温度变化的规律。我们计算了银(Ag)、铝(Al)、铜(Cu)和铅(Pb)在不同尺寸下的体积热膨胀系数。研究了温度对银(Ag)、金(Au)、镍(Ni)、铜(Cu)和硅(Si)杨氏模量的影响。将计算结果与已有的实验数据进行了比较,证实了体积热膨胀系数随纳米材料尺寸的减小而增大。杨氏模量随温度的升高呈线性递减,表明纳米材料的杨氏模量具有负温度系数。
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Thermo-physical Behavior of Nanomaterials with the Change in Size and Shape
Thermo elastic properties of nanomaterials has been very interesting among the researchers during the last decade, still it is a great challenge to predict the exact thermoelastic behaviour of nanomaterials. In the present work we have studied the volume thermal expansion coefficient of low dimensional solid and the variation of Young’s modulus with change in temperature for different shapes of nanomaterials by considering the effect of packing factor. We have computed the volume thermal expansion coefficient of Silver (Ag), Aluminum (Al), Copper (Cu), and Lead (Pb) with their varying size. The effect of temperature on Young’s modulus of Silver (Ag), Gold (Au), Nickel (Ni), Copper (Cu) and Silicon (Si) has also been studied. The computed results are compared with available experimental data which confirms that the volume thermal expansion coefficient increases with reduction in size of the nanomaterials. It has been also observed that the Young’s modulus has linear decrement with increase in temperature which indicates that Young’s modulus of nanomaterials has negative temperature coefficient.
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来源期刊
CiteScore
1.50
自引率
12.50%
发文量
35
期刊介绍: The purpose and scope of the International Journal of Thermodynamics is · to provide a forum for the publication of original theoretical and applied work in the field of thermodynamics as it relates to systems, states, processes, and both non-equilibrium and equilibrium phenomena at all temporal and spatial scales. · to provide a multidisciplinary and international platform for the dissemination to academia and industry of both scientific and engineering contributions, which touch upon a broad class of disciplines that are foundationally linked to thermodynamics and the methods and analyses derived there from. · to assess how both the first and particularly the second laws of thermodynamics touch upon these disciplines. · to highlight innovative & pioneer research in the field of thermodynamics in the following subjects (but not limited to the following, novel research in new areas are strongly suggested): o Entropy in thermodynamics and information theory. o Thermodynamics in process intensification. o Biothermodynamics (topics such as self-organization far from equilibrium etc.) o Thermodynamics of nonadditive systems. o Nonequilibrium thermal complex systems. o Sustainable design and thermodynamics. o Engineering thermodynamics. o Energy.
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